Flavin Receptors. Effect of the Acidity of Melamine Derivatives Bearing a 2-Arylguanidinium Ion on 6-Azaflavin Binding in Chloroform

The pKa's of melamine derivatives bearing a 2-arylguanidinium ion and their binding constants for 6-aza-10-dodecylisoalloxazine (6-azaflavin) were nicely correlated with the Hammett σ of the substituents. However, the rates of the oxidations of N-benzyl-1,4-dihydronicotinamide (BNAH) and dithio...

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Published in:Bulletin of the Chemical Society of Japan 2000-11, Vol.73 (11), p.2539-2542
Main Authors: Moriya, Hideki, Kajiki, Takeshi, Watanabe, Shigeki, Kondo, Shin-ichi, Yano, Yumihiko
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cited_by cdi_FETCH-LOGICAL-c393t-853dc965669af7bad9b55d0e85f629b6c06316e80e7e93fb5dfeb79a2f3bd4023
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creator Moriya, Hideki
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description The pKa's of melamine derivatives bearing a 2-arylguanidinium ion and their binding constants for 6-aza-10-dodecylisoalloxazine (6-azaflavin) were nicely correlated with the Hammett σ of the substituents. However, the rates of the oxidations of N-benzyl-1,4-dihydronicotinamide (BNAH) and dithiothreitol (DTT) by 6-azaflavin were not affected by the substituents of the receptors in CHCl3.
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title Flavin Receptors. Effect of the Acidity of Melamine Derivatives Bearing a 2-Arylguanidinium Ion on 6-Azaflavin Binding in Chloroform
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