Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions

This review focuses on chelation-assisted regioselective C–H activation with C–C or/and C–N bond formation using nickel(0) or -(II) as the catalysts, where bidentate directing groups play a key role in the successful transformation. A 2-pyridinylmethylamine or an 8-aminoquinoline moiety are the more...

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Bibliographic Details
Published in:Chemistry letters 2015-04, Vol.44 (4), p.410-421
Main Authors: Castro, Luis C Misal, Chatani, Naoto
Format: Article
Language:English
Subjects:
Catalytic C-H Activation
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Summary:This review focuses on chelation-assisted regioselective C–H activation with C–C or/and C–N bond formation using nickel(0) or -(II) as the catalysts, where bidentate directing groups play a key role in the successful transformation. A 2-pyridinylmethylamine or an 8-aminoquinoline moiety are the more powerful auxiliaries among the directing groups examined.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.150024