In-situ Iodination of Organoarsenic Homocycles: Facile Synthesis of 9-Arsafluorene

We developed an in-situ iodination of organoarsenic homocycles for facile and general As–C bond formation. Quantitative in-situ generations of arsenic diiodides from organoarsenic homocycles and iodine were confirmed by 1H NMR analysis. 9-Phenyl- and 9-methyl-9-arsafluorenes were prepared by this me...

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Bibliographic Details
Published in:Chemistry letters 2015-11, Vol.44 (11), p.1476-1478
Main Authors: Kato, Takuji, Tanaka, Susumu, Naka, Kensuke
Format: Article
Language:English
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Summary:We developed an in-situ iodination of organoarsenic homocycles for facile and general As–C bond formation. Quantitative in-situ generations of arsenic diiodides from organoarsenic homocycles and iodine were confirmed by 1H NMR analysis. 9-Phenyl- and 9-methyl-9-arsafluorenes were prepared by this method and their optical properties were studied.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.150657