A Novel Discrete d-f Heterobinuclear Complex Designed from Tetrahedrally Distorted [Cu(salabza)](H2salabza: N,N′-Bis(salicylidene)-2-aminobenzylamine) and [Gd(hfac)3]

Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-aminobenzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectiv...

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Bibliographic Details
Published in:Chemistry letters 1998-09, Vol.27 (9), p.911-912
Main Authors: Sasaki, Miwa, Horiuchi, Hiroaki, Kumagai, Motoko, Sakamoto, Masatomi, Sakiyama, Hiroshi, Nishida, Yuzo, Sadaoka, Yoshihiko, Ohba, Masaaki, Okawa, Hisashi
Format: Article
Language:English
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Summary:Binuclear Cu(II)-Gd(III) complex, [Cu(salabza)Gd(hfac)3], was synthesized by the combination of a tetrahedrally distorted Cu(II) complex, [Cu(salabza)] with [Gd(hfac)3]·2H2O, where H2salabza and Hhfac denote N,N′-bis(salicylidene)-2-aminobenzylamine and 1,1,1,5,5,5-hexafluoroacetylacetone, respectively. Structural analysis revealed that the complex has the long intermolecular metal-metal distances enough to be regarded as a discrete one.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1998.911