Carbon-carbon Bond Forming Reactions of μ-Vinylcarbenedipalladium Complexes

μ-η3-Vinyl(phenyl)carbenedipalladium complex reacted with tetraphenyltin to give a η3-diphenylallylpalladium complex through reductive elimination, and with internal alkynes to give μ-η2:η3-dienylcarbene complexes through migratory insertion.

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Bibliographic Details
Published in:Chemistry letters 1999-02, Vol.28 (2), p.123-124
Main Authors: Ogoshi, Sensuke, Tsutsumi, Ken, Shinagawa, Tsutomu, Kakiuchi, Kiyomi, Kurosawa, Hideo
Format: Article
Language:English
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Description
Summary:μ-η3-Vinyl(phenyl)carbenedipalladium complex reacted with tetraphenyltin to give a η3-diphenylallylpalladium complex through reductive elimination, and with internal alkynes to give μ-η2:η3-dienylcarbene complexes through migratory insertion.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1999.123