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31P{27Al} MQMAS/HETCOR NMR Study on Structure of Amorphous AlPO4

A solid-state NMR method combining 27Al multiple-quantum magic-angle spinning (MQMAS) and 31P{27Al} heteronuclear correlation (HETCOR) has been applied for the structural analysis of amorphous AlPO4. We obtained a correlation between the isotropic chemical shifts of 31P in PO4 and of 27Al in each Al...

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Bibliographic Details
Published in:Chemistry letters 2005-10, Vol.34 (10), p.1380-1381
Main Authors: Iijima, Takahiro, Kanehashi, Koji, Saito, Koji, Hatakeyama, Moriaki, Nemoto, Takahiro, Shimizu, Tadashi, Ohki, Shinobu
Format: Article
Language:English
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Summary:A solid-state NMR method combining 27Al multiple-quantum magic-angle spinning (MQMAS) and 31P{27Al} heteronuclear correlation (HETCOR) has been applied for the structural analysis of amorphous AlPO4. We obtained a correlation between the isotropic chemical shifts of 31P in PO4 and of 27Al in each AlOn (n = 4, 5, and 6) distributed by the amorphous structure.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2005.1380