Fe3+-K-10 Montmorillonite Clay Catalyzed Friedel–Crafts Reaction of Unactivated Baylis–Hillman Adducts: An Efficient Stereoselective Synthesis of Trisubstituted Alkenes Containing a Benzyl Substituent

The stereoselective synthesis of trisubstituted alkenes containing a benzyl substituent has been achieved by employing Friedel–Craft reaction of aromatic compounds with unactivated Baylis–Hillman adducts in the presence of Fe3+-K-10 montmorillonite clay as a heterogeneous catalyst. The catalyst can...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry letters 2005-11, Vol.34 (11), p.1492-1493
Main Authors: Das, Biswanath, Majhi, Anjoy, Banerjee, Joydeep, Chowdhury, Nikhil, Venkateswarlu, Katta
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The stereoselective synthesis of trisubstituted alkenes containing a benzyl substituent has been achieved by employing Friedel–Craft reaction of aromatic compounds with unactivated Baylis–Hillman adducts in the presence of Fe3+-K-10 montmorillonite clay as a heterogeneous catalyst. The catalyst can be recovered and reused.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2005.1492