Oxidative Arylation Mediated by Naphthalene-1,8-diylbis(diphenylmethylium): Synthetic Route to Triarylsulfonium Salts

Dicationic species, naphthalene-1,8-diylbis(diphenylmethylium), successfully promoted oxidative arylation of the sulfur atom in (4-N,N-dialkylaminophenyl) phenyl sulfides with (4-N,N-dialkylaminopheny)silanes, affording triarylsulfonium salts in good yield.

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Bibliographic Details
Published in:Chemistry letters 2010, Vol.39 (1), p.56-57
Main Authors: Tanabe, Hiroyuki, Kawai, Takaharu, Saitoh, Terunobu, Ichikawa, Junji
Format: Article
Language:English
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Summary:Dicationic species, naphthalene-1,8-diylbis(diphenylmethylium), successfully promoted oxidative arylation of the sulfur atom in (4-N,N-dialkylaminophenyl) phenyl sulfides with (4-N,N-dialkylaminopheny)silanes, affording triarylsulfonium salts in good yield.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2010.56