Continuous Laser-Excited Photothermal Spectrometry of CdS x Se 1–x Doped Glasses

Photothermal lens measurements and finite element modeling are used to examine the physical changes taking place in optical filter glasses. Colored glass and neutral density filters are found to have a strong positive temperature-dependent refractive index change. The overall positive refractive ind...

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Bibliographic Details
Published in:Applied spectroscopy 2007-12, Vol.61 (12), p.1373-1378
Main Authors: Dada, Oluwatosin O., Jorgensen, Matthew R., Bialkowski, Stephen E.
Format: Article
Language:English
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Summary:Photothermal lens measurements and finite element modeling are used to examine the physical changes taking place in optical filter glasses. Colored glass and neutral density filters are found to have a strong positive temperature-dependent refractive index change. The overall positive refractive index change is thought to be a consequence of complex counteracting factors: stress-induced birefringence, polarizability, structural network, and temperature-dependent carrier density changes in the CdS x Se 1–x microcrystals that produce optical properties of these glasses. Finite element analysis (FEA) modeling is used to examine the temperature profiles and the goodness of the semi-infinite thermal diffusion solution normally used for thermal lens experiments. The results of FEA were used to optimize experimental parameters and calculate values of d n/d T for the glass by comparison with standard liquid samples.
ISSN:0003-7028
1943-3530
DOI:10.1366/000370207783292253