Structural, Spectroscopic and Hirshfeld Surface Analysis of Anilinium Malonate

The comprehensive elucidation of the crystal structure, vibrational and Hirshfeld surface analysis of new crystalline product anilinium malonate C6H5NH3 +. C3H3O4 – are presented in this communication. Single crystals of anilinium malonate have been grown by the method of slow evaporation at room te...

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Bibliographic Details
Published in:Asian journal of chemistry 2019-03, Vol.31 (4), p.860-872
Main Authors: Anjalin, F. Mary, Kanagathara, N., Marchewka, M.K., Srinivasan, T.
Format: Article
Language:English
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Summary:The comprehensive elucidation of the crystal structure, vibrational and Hirshfeld surface analysis of new crystalline product anilinium malonate C6H5NH3 +. C3H3O4 – are presented in this communication. Single crystals of anilinium malonate have been grown by the method of slow evaporation at room temperature. Single crystal XRD study has been carried out to study the structural properties of the grown crystal and it reveals that the crystal crystallizes in the monoclinic system with centrosymmetric space group P2(1)/n. Room temperature powder infrared and Raman spectra of the aniline malonic acid molecular complex (1:1) were carried out. All the characteristic frequencies present in the crystal gives the notable vibrational effect. Hirshfeld surface analysis has been carried out to know the intercontact between the atoms in the structure of the grown crystal.
ISSN:0970-7077
0975-427X
DOI:10.14233/ajchem.2019.21839