Structural Analysis using X-Ray Diffraction and FTIR Spectroscopic Studies on Mn2+ Substituted CaWO4 Materials Synthesized by Coprecipitation Method

Present day technology requires synthesis of materials with low energy consumption, free mercury pollution and its reliability. A novel material with control of crystallite size, composition and simple for white light relies in synthesis of materials. The present focus of article attributes series o...

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Published in:Asian journal of chemistry 2019-11, Vol.32 (1), p.49-52
Main Authors: Rao, M. Jaganadha, Murthy, K.S.R., Shankar Kumar, Ch. Ravi, Jha, Anjali, Choudary, G.S.V.R.K., Varma, M. Chaitanya
Format: Article
Language:English
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Summary:Present day technology requires synthesis of materials with low energy consumption, free mercury pollution and its reliability. A novel material with control of crystallite size, composition and simple for white light relies in synthesis of materials. The present focus of article attributes series of manganese doped Ca1-xMnxWO4 luminescent materials with co-precipitation method. Reported studies attempts with change in structure of calcium tungstate (CaWO4) are observed with dopants like Eu3+, Eu2+, Tb3+, etc. However the effect of Mn2+ on structural properties of CaWO4 are quite interesting. The synthesized samples were characterized with X-ray diffraction for lattice parameters, crystallite size and FTIR studies for bonding mechanism of O-W-O stretching and W-O-W bridge bond. Rietveld profile refinement of XRD patterns using MAUD program Ca1-xMnxWO4 revealed the Scheelite type structure with C4h point group and I41/a space group. Characterization studies reveal that doping of Mn2+ doping upto 0.1 in place of Ca2+ will not change the phase of Scheelite structure.
ISSN:0970-7077
0975-427X
DOI:10.14233/ajchem.2020.22199