Synthesis and Properties of Two Fe(III) Coordination Polymers Based on 2-Amino-4-methylthiazole, 2-Mercaptobenzothiazole and Aromatic Polycarboxylate

Two of coordination polymers of the general formula [Fe(BDC)(AMTZ)Cl]·2H2O and [Fe(BDC)(MBT)Cl]·H2O, BDC = 1,4-benzenedicarboxylic acid, AMTZ = 2-amino-4-methyl-thiazole and MBT = 2-mercaptobenzothiazole, have been synthesized and characterized. Structure of both coordination polymers has been evalu...

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Bibliographic Details
Published in:Asian journal of chemistry 2020-10, Vol.32 (10), p.2502-2506
Main Authors: Al-Fakeh, Maged S., Amiri, Nesrine, Al-Hakemi, Ahmed N., Saeed, Saeed El-Sayed, Albadri, Abuzar E.A.E.
Format: Article
Language:English
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Summary:Two of coordination polymers of the general formula [Fe(BDC)(AMTZ)Cl]·2H2O and [Fe(BDC)(MBT)Cl]·H2O, BDC = 1,4-benzenedicarboxylic acid, AMTZ = 2-amino-4-methyl-thiazole and MBT = 2-mercaptobenzothiazole, have been synthesized and characterized. Structure of both coordination polymers has been evaluated on the basis of elemental analysis, thermal, FT-IR, UV-vis spectra and the charges been carried by the atoms, caused a dipole moment of 2.4346 debye and total energy -382 × 103 Kcal mol-1. Biological activity of the two synthesized complexes was tested against some fungal and bacterial strains
ISSN:0970-7077
0975-427X
DOI:10.14233/ajchem.2020.22767