Limiting molar conductivity behaviour of ENR-50 electrolyte in mixed solvent system at ambient temperature

The present research investigates the behaviour of the limiting molar conductivity (Λo) of ENR-50/LiClO4 in a mixed solvent systemcomprising tetrahydrofuran (THF) and acetonitrile (ACN) at ambient temperature. The study uses the power law, to determine the Λovalue of ENR-50/LiClO4/THF:ACN at a speci...

Full description

Saved in:
Bibliographic Details
Published in:Asian journal of chemistry 2023-12, Vol.35 (12), p.3111-3117
Main Authors: Mohd Tajudin, Mohd Afieq, Hanibah, Hussein, Darji, Dazylah
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 3117
container_issue 12
container_start_page 3111
container_title Asian journal of chemistry
container_volume 35
creator Mohd Tajudin, Mohd Afieq
Hanibah, Hussein
Darji, Dazylah
description The present research investigates the behaviour of the limiting molar conductivity (Λo) of ENR-50/LiClO4 in a mixed solvent systemcomprising tetrahydrofuran (THF) and acetonitrile (ACN) at ambient temperature. The study uses the power law, to determine the Λovalue of ENR-50/LiClO4/THF:ACN at a specific reference salt concentration. The ENR-50/LiClO4 electrolyte system was prepared witha fixed THF:ACN ratio of 8:2, at different ENR-50 concentration of range between 0.001-0.003 g/cm3. The correlation values obtainedfor the three polymer concentrations ranged from 0.9959 to 0.9966. Regression analysis revealed that as the polymer concentrationincreases, the Λo decreases, indicating an inverse relationship which suggesting an enhanced ion dissociation due to an increase in total free-moving ions within the liquid polymer electrolyte system. The characterization of ENR-50/LiClO4/THF:ACN was verified through ATR-FTIR spectroscopy, confirming the ion dipole interaction between the C-O-C group of ENR-50 and Li ions.
doi_str_mv 10.14233/ajchem.2023.30627
format article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_14233_ajchem_2023_30627</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_14233_ajchem_2023_30627</sourcerecordid><originalsourceid>FETCH-LOGICAL-c113t-ff16d60623a902978a27f68c32027c8b5ec387f77744107e4abab6dd908225b43</originalsourceid><addsrcrecordid>eNotkMtqwzAQRUVpoSHND3SlH3Cqh-2xlyWkDwgtlBa6M7I8ahQsK0hKqP--TtLZzNy7GDiHkHvOljwXUj6ond6iWwom5FKyUsAVmbEaiiwX8H19vlkGDOCWLGLcsWlKXggQM7LbWGeTHX6o870KVPuhO-hkjzaNtMWtOlp_CNQbun77yApGsUedgu_HhNQO1Nlf7Gj0_RGHROMYEzqqElWutadminsMKh0C3pEbo_qIi_89J19P68_VS7Z5f35dPW4yzblMmTG87MqJQqqaiRoqJcCUlZYTHuiqLVDLCgwA5DlngLlqVVt2Xc0qIYo2l3MiLn918DEGNM0-WKfC2HDWnIU1F2HNSVhzFib_AAJSYRw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Limiting molar conductivity behaviour of ENR-50 electrolyte in mixed solvent system at ambient temperature</title><source>Alma/SFX Local Collection</source><creator>Mohd Tajudin, Mohd Afieq ; Hanibah, Hussein ; Darji, Dazylah</creator><creatorcontrib>Mohd Tajudin, Mohd Afieq ; Hanibah, Hussein ; Darji, Dazylah</creatorcontrib><description>The present research investigates the behaviour of the limiting molar conductivity (Λo) of ENR-50/LiClO4 in a mixed solvent systemcomprising tetrahydrofuran (THF) and acetonitrile (ACN) at ambient temperature. The study uses the power law, to determine the Λovalue of ENR-50/LiClO4/THF:ACN at a specific reference salt concentration. The ENR-50/LiClO4 electrolyte system was prepared witha fixed THF:ACN ratio of 8:2, at different ENR-50 concentration of range between 0.001-0.003 g/cm3. The correlation values obtainedfor the three polymer concentrations ranged from 0.9959 to 0.9966. Regression analysis revealed that as the polymer concentrationincreases, the Λo decreases, indicating an inverse relationship which suggesting an enhanced ion dissociation due to an increase in total free-moving ions within the liquid polymer electrolyte system. The characterization of ENR-50/LiClO4/THF:ACN was verified through ATR-FTIR spectroscopy, confirming the ion dipole interaction between the C-O-C group of ENR-50 and Li ions.</description><identifier>ISSN: 0970-7077</identifier><identifier>EISSN: 0975-427X</identifier><identifier>DOI: 10.14233/ajchem.2023.30627</identifier><language>eng</language><ispartof>Asian journal of chemistry, 2023-12, Vol.35 (12), p.3111-3117</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-5882-1018 ; 0009-0006-8279-6832 ; 0000-0002-4681-2886</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Mohd Tajudin, Mohd Afieq</creatorcontrib><creatorcontrib>Hanibah, Hussein</creatorcontrib><creatorcontrib>Darji, Dazylah</creatorcontrib><title>Limiting molar conductivity behaviour of ENR-50 electrolyte in mixed solvent system at ambient temperature</title><title>Asian journal of chemistry</title><description>The present research investigates the behaviour of the limiting molar conductivity (Λo) of ENR-50/LiClO4 in a mixed solvent systemcomprising tetrahydrofuran (THF) and acetonitrile (ACN) at ambient temperature. The study uses the power law, to determine the Λovalue of ENR-50/LiClO4/THF:ACN at a specific reference salt concentration. The ENR-50/LiClO4 electrolyte system was prepared witha fixed THF:ACN ratio of 8:2, at different ENR-50 concentration of range between 0.001-0.003 g/cm3. The correlation values obtainedfor the three polymer concentrations ranged from 0.9959 to 0.9966. Regression analysis revealed that as the polymer concentrationincreases, the Λo decreases, indicating an inverse relationship which suggesting an enhanced ion dissociation due to an increase in total free-moving ions within the liquid polymer electrolyte system. The characterization of ENR-50/LiClO4/THF:ACN was verified through ATR-FTIR spectroscopy, confirming the ion dipole interaction between the C-O-C group of ENR-50 and Li ions.</description><issn>0970-7077</issn><issn>0975-427X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNotkMtqwzAQRUVpoSHND3SlH3Cqh-2xlyWkDwgtlBa6M7I8ahQsK0hKqP--TtLZzNy7GDiHkHvOljwXUj6ond6iWwom5FKyUsAVmbEaiiwX8H19vlkGDOCWLGLcsWlKXggQM7LbWGeTHX6o870KVPuhO-hkjzaNtMWtOlp_CNQbun77yApGsUedgu_HhNQO1Nlf7Gj0_RGHROMYEzqqElWutadminsMKh0C3pEbo_qIi_89J19P68_VS7Z5f35dPW4yzblMmTG87MqJQqqaiRoqJcCUlZYTHuiqLVDLCgwA5DlngLlqVVt2Xc0qIYo2l3MiLn918DEGNM0-WKfC2HDWnIU1F2HNSVhzFib_AAJSYRw</recordid><startdate>20231202</startdate><enddate>20231202</enddate><creator>Mohd Tajudin, Mohd Afieq</creator><creator>Hanibah, Hussein</creator><creator>Darji, Dazylah</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5882-1018</orcidid><orcidid>https://orcid.org/0009-0006-8279-6832</orcidid><orcidid>https://orcid.org/0000-0002-4681-2886</orcidid></search><sort><creationdate>20231202</creationdate><title>Limiting molar conductivity behaviour of ENR-50 electrolyte in mixed solvent system at ambient temperature</title><author>Mohd Tajudin, Mohd Afieq ; Hanibah, Hussein ; Darji, Dazylah</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c113t-ff16d60623a902978a27f68c32027c8b5ec387f77744107e4abab6dd908225b43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Mohd Tajudin, Mohd Afieq</creatorcontrib><creatorcontrib>Hanibah, Hussein</creatorcontrib><creatorcontrib>Darji, Dazylah</creatorcontrib><collection>CrossRef</collection><jtitle>Asian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohd Tajudin, Mohd Afieq</au><au>Hanibah, Hussein</au><au>Darji, Dazylah</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Limiting molar conductivity behaviour of ENR-50 electrolyte in mixed solvent system at ambient temperature</atitle><jtitle>Asian journal of chemistry</jtitle><date>2023-12-02</date><risdate>2023</risdate><volume>35</volume><issue>12</issue><spage>3111</spage><epage>3117</epage><pages>3111-3117</pages><issn>0970-7077</issn><eissn>0975-427X</eissn><abstract>The present research investigates the behaviour of the limiting molar conductivity (Λo) of ENR-50/LiClO4 in a mixed solvent systemcomprising tetrahydrofuran (THF) and acetonitrile (ACN) at ambient temperature. The study uses the power law, to determine the Λovalue of ENR-50/LiClO4/THF:ACN at a specific reference salt concentration. The ENR-50/LiClO4 electrolyte system was prepared witha fixed THF:ACN ratio of 8:2, at different ENR-50 concentration of range between 0.001-0.003 g/cm3. The correlation values obtainedfor the three polymer concentrations ranged from 0.9959 to 0.9966. Regression analysis revealed that as the polymer concentrationincreases, the Λo decreases, indicating an inverse relationship which suggesting an enhanced ion dissociation due to an increase in total free-moving ions within the liquid polymer electrolyte system. The characterization of ENR-50/LiClO4/THF:ACN was verified through ATR-FTIR spectroscopy, confirming the ion dipole interaction between the C-O-C group of ENR-50 and Li ions.</abstract><doi>10.14233/ajchem.2023.30627</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-5882-1018</orcidid><orcidid>https://orcid.org/0009-0006-8279-6832</orcidid><orcidid>https://orcid.org/0000-0002-4681-2886</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0970-7077
ispartof Asian journal of chemistry, 2023-12, Vol.35 (12), p.3111-3117
issn 0970-7077
0975-427X
language eng
recordid cdi_crossref_primary_10_14233_ajchem_2023_30627
source Alma/SFX Local Collection
title Limiting molar conductivity behaviour of ENR-50 electrolyte in mixed solvent system at ambient temperature
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-16T21%3A46%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Limiting%20molar%20conductivity%20behaviour%20of%20ENR-50%20electrolyte%20in%20mixed%20solvent%20system%20at%20ambient%20temperature&rft.jtitle=Asian%20journal%20of%20chemistry&rft.au=Mohd%20Tajudin,%20Mohd%20Afieq&rft.date=2023-12-02&rft.volume=35&rft.issue=12&rft.spage=3111&rft.epage=3117&rft.pages=3111-3117&rft.issn=0970-7077&rft.eissn=0975-427X&rft_id=info:doi/10.14233/ajchem.2023.30627&rft_dat=%3Ccrossref%3E10_14233_ajchem_2023_30627%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c113t-ff16d60623a902978a27f68c32027c8b5ec387f77744107e4abab6dd908225b43%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true