Luminescence properties of Eu 2+ and Sm 3+ co-doped in KBaPO 4

• Published in: High temperature materials and processes 2021-11, Vol.40 (1), p.389-396
• Main Authors: Xu, Yingwei, Zhang, Tingting, Zheng, Li, Zou, Ailing
• Format: Article
• Language: English
• ISSN: 2191-0324; 2191-0324
• DOI: 10.1515/htmp-2021-0046

KBaPO 4 :Eu 2+ /Sm 3+ phosphor was synthesized via the high-temperature solid-phase reaction method. The structural properties, surface morphology, and optical properties of the synthesized samples were obtained by the X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and fluorescence measurements. The XRD patterns indicate that the crystal structure of KBaPO 4 has not been changed by co-doped with two rare-earth ions. Under the excitation of 400 nm, the Eu 2+ and Sm 3+ co-doped KBaPO 4 phosphors showed typical emission peaks at 430 (blue), 562 (yellow), and 600 nm (red). Meanwhile, with the increase of the Sm 3+ content, the photoluminescent (PL) emission intensity of Sm 3+ increased until the content reaches 0.12. However, the PL intensity of Eu 2+ ions gradually decreased, which indicated that there was a possible energy transfer between the two ions. Therefore, the obtained results indicated that Eu 2+ /Sm 3+ co-doped KBaPO 4 is a promising phosphor for the use in white light-emitting diodes with near ultraviolet chips.