A simple determination of whole-rock major- and trace-element composition for peridotite by micro-XRF spectrometer and ICP-MS using fused-glass bead

A simple analytical procedure for determination of whole-rock major- and trace-element composition by micro-X-ray fluorescence (μXRF) spectrometer and inductively coupled plasma-mass spectrometer (ICP-MS) using fused-glass bead (sample + lithium tetraborate) is presented. In the case of peridotites,...

Full description

Saved in:
Bibliographic Details
Published in:GEOCHEMICAL JOURNAL 2020, Vol.54(2), pp.81-90
Main Authors: Akizawa, Norikatsu, Ishikawa, Akira, Kogiso, Tetsu
Format: Article
Language:English
Subjects:
acid digestion
lithium tetraborate glass
mantle xenolith
Tahiti-Moorea islands
whole-rock composition
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a561t-e87dbb5faec32d15f6000f1fae49a24006f12c88955019cb27bca7138882a9a43
cites cdi_FETCH-LOGICAL-a561t-e87dbb5faec32d15f6000f1fae49a24006f12c88955019cb27bca7138882a9a43
container_end_page 90
container_issue 2
container_start_page 81
container_title GEOCHEMICAL JOURNAL
container_volume 54
creator Akizawa, Norikatsu
Ishikawa, Akira
Kogiso, Tetsu
description A simple analytical procedure for determination of whole-rock major- and trace-element composition by micro-X-ray fluorescence (μXRF) spectrometer and inductively coupled plasma-mass spectrometer (ICP-MS) using fused-glass bead (sample + lithium tetraborate) is presented. In the case of peridotites, chromian spinel (Cr-spinel) is one of the minerals resistant to acids and interferes with accurate and reproducible determination of whole-rock composition. Such resistant minerals were not observed in the fused-glass beads prepared here, suggesting complete digestion of the samples including Cr-spinels. The μXRF spectrometer was employed to determine SiO2, MgO, and total Fe2O3 contents with the fused-glass beads. They were subsequently dissolved into a nitric acid solution to analyze thirty seven elements, Na, Al, P, K, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Rb, Sr, Y, Zr, Nb, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, Pb, Th, and U with sector magnetic field ICP-MS (ICP-SFMS) and Q-pole mass filter ICP-MS (ICP-QMS). The analytical procedures were optimized and evaluated with geological reference materials of JP-1 and BIR-1a, and applied to various mantle xenoliths (lherzolite, harzburgite, dunite, wehrlite, olivine clinopyroxenite, and orthopyroxenite) from Tahiti and Moorea islands (Society Archipelago). Since only fused-glass beads are required as an analytical target to determine whole-rock major- and trace-element compositions, the sample amount consumed through the series of analytical procedure can be constrained to a minute amount (e.g.,
doi_str_mv 10.2343/geochemj.2.0587
format article
fullrecord <record><control><sourceid>jstage_cross</sourceid><recordid>TN_cdi_crossref_primary_10_2343_geochemj_2_0587</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>article_geochemj_54_2_54_2_0587_article_char_en</sourcerecordid><originalsourceid>FETCH-LOGICAL-a561t-e87dbb5faec32d15f6000f1fae49a24006f12c88955019cb27bca7138882a9a43</originalsourceid><addsrcrecordid>eNpFkMtOwzAQRS0EEuWxZusfcLGduHGWqOIlgUA8JHbRxBm3LnEc2UaI_-CDactrM6PR3HNndAk5EXwqi7I4XWAwS_SrqZxypasdMhFac6bqqtglE87FjFWcy31ykNKK86KslZ6QzzOanB97pB1mjN4NkF0YaLD0fRl6ZDGYV-phFSKjMHQ0RzDIsEePQ6Ym-DEkt0VsiHTE6LqQXUbaflDvTAzs5eGCphFNjsFvbmxtruf37PaRviU3LKh9S9ixRQ8p0RahOyJ7FvqExz_9kDxfnD_Nr9jN3eX1_OyGgZqJzFBXXdsqC2gK2QllZ5xzK9ZzWYMsOZ9ZIY3WtVJc1KaVVWugEoXWWkINZXFITr9912-mFNE2Y3Qe4kcjeLMJtfkNtZHNJtQ1cf5NrFKGBf7pIWZnevzXq3KNbMuG-9ubJcQGh-ILl0mIjw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A simple determination of whole-rock major- and trace-element composition for peridotite by micro-XRF spectrometer and ICP-MS using fused-glass bead</title><source>Free Full-Text Journals in Chemistry</source><creator>Akizawa, Norikatsu ; Ishikawa, Akira ; Kogiso, Tetsu</creator><creatorcontrib>Akizawa, Norikatsu ; Ishikawa, Akira ; Kogiso, Tetsu</creatorcontrib><description>A simple analytical procedure for determination of whole-rock major- and trace-element composition by micro-X-ray fluorescence (μXRF) spectrometer and inductively coupled plasma-mass spectrometer (ICP-MS) using fused-glass bead (sample + lithium tetraborate) is presented. In the case of peridotites, chromian spinel (Cr-spinel) is one of the minerals resistant to acids and interferes with accurate and reproducible determination of whole-rock composition. Such resistant minerals were not observed in the fused-glass beads prepared here, suggesting complete digestion of the samples including Cr-spinels. The μXRF spectrometer was employed to determine SiO2, MgO, and total Fe2O3 contents with the fused-glass beads. They were subsequently dissolved into a nitric acid solution to analyze thirty seven elements, Na, Al, P, K, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Rb, Sr, Y, Zr, Nb, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, Pb, Th, and U with sector magnetic field ICP-MS (ICP-SFMS) and Q-pole mass filter ICP-MS (ICP-QMS). The analytical procedures were optimized and evaluated with geological reference materials of JP-1 and BIR-1a, and applied to various mantle xenoliths (lherzolite, harzburgite, dunite, wehrlite, olivine clinopyroxenite, and orthopyroxenite) from Tahiti and Moorea islands (Society Archipelago). Since only fused-glass beads are required as an analytical target to determine whole-rock major- and trace-element compositions, the sample amount consumed through the series of analytical procedure can be constrained to a minute amount (e.g., &lt;0.4 g). The analytical procedures presented here are considered appropriate for tiny and/or precious samples, such as mantle xenoliths and rocks collected by dredging, diving, and drilling from the world’s ocean basins.</description><identifier>ISSN: 0016-7002</identifier><identifier>EISSN: 1880-5973</identifier><identifier>DOI: 10.2343/geochemj.2.0587</identifier><language>eng</language><publisher>GEOCHEMICAL SOCIETY OF JAPAN</publisher><subject>acid digestion ; lithium tetraborate glass ; mantle xenolith ; Tahiti-Moorea islands ; whole-rock composition</subject><ispartof>GEOCHEMICAL JOURNAL, 2020, Vol.54(2), pp.81-90</ispartof><rights>2020 by The Geochemical Society of Japan</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a561t-e87dbb5faec32d15f6000f1fae49a24006f12c88955019cb27bca7138882a9a43</citedby><cites>FETCH-LOGICAL-a561t-e87dbb5faec32d15f6000f1fae49a24006f12c88955019cb27bca7138882a9a43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,4010,27904,27905,27906</link.rule.ids></links><search><creatorcontrib>Akizawa, Norikatsu</creatorcontrib><creatorcontrib>Ishikawa, Akira</creatorcontrib><creatorcontrib>Kogiso, Tetsu</creatorcontrib><title>A simple determination of whole-rock major- and trace-element composition for peridotite by micro-XRF spectrometer and ICP-MS using fused-glass bead</title><title>GEOCHEMICAL JOURNAL</title><addtitle>Geochem. J.</addtitle><description>A simple analytical procedure for determination of whole-rock major- and trace-element composition by micro-X-ray fluorescence (μXRF) spectrometer and inductively coupled plasma-mass spectrometer (ICP-MS) using fused-glass bead (sample + lithium tetraborate) is presented. In the case of peridotites, chromian spinel (Cr-spinel) is one of the minerals resistant to acids and interferes with accurate and reproducible determination of whole-rock composition. Such resistant minerals were not observed in the fused-glass beads prepared here, suggesting complete digestion of the samples including Cr-spinels. The μXRF spectrometer was employed to determine SiO2, MgO, and total Fe2O3 contents with the fused-glass beads. They were subsequently dissolved into a nitric acid solution to analyze thirty seven elements, Na, Al, P, K, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Rb, Sr, Y, Zr, Nb, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, Pb, Th, and U with sector magnetic field ICP-MS (ICP-SFMS) and Q-pole mass filter ICP-MS (ICP-QMS). The analytical procedures were optimized and evaluated with geological reference materials of JP-1 and BIR-1a, and applied to various mantle xenoliths (lherzolite, harzburgite, dunite, wehrlite, olivine clinopyroxenite, and orthopyroxenite) from Tahiti and Moorea islands (Society Archipelago). Since only fused-glass beads are required as an analytical target to determine whole-rock major- and trace-element compositions, the sample amount consumed through the series of analytical procedure can be constrained to a minute amount (e.g., &lt;0.4 g). The analytical procedures presented here are considered appropriate for tiny and/or precious samples, such as mantle xenoliths and rocks collected by dredging, diving, and drilling from the world’s ocean basins.</description><subject>acid digestion</subject><subject>lithium tetraborate glass</subject><subject>mantle xenolith</subject><subject>Tahiti-Moorea islands</subject><subject>whole-rock composition</subject><issn>0016-7002</issn><issn>1880-5973</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNpFkMtOwzAQRS0EEuWxZusfcLGduHGWqOIlgUA8JHbRxBm3LnEc2UaI_-CDactrM6PR3HNndAk5EXwqi7I4XWAwS_SrqZxypasdMhFac6bqqtglE87FjFWcy31ykNKK86KslZ6QzzOanB97pB1mjN4NkF0YaLD0fRl6ZDGYV-phFSKjMHQ0RzDIsEePQ6Ym-DEkt0VsiHTE6LqQXUbaflDvTAzs5eGCphFNjsFvbmxtruf37PaRviU3LKh9S9ixRQ8p0RahOyJ7FvqExz_9kDxfnD_Nr9jN3eX1_OyGgZqJzFBXXdsqC2gK2QllZ5xzK9ZzWYMsOZ9ZIY3WtVJc1KaVVWugEoXWWkINZXFITr9912-mFNE2Y3Qe4kcjeLMJtfkNtZHNJtQ1cf5NrFKGBf7pIWZnevzXq3KNbMuG-9ubJcQGh-ILl0mIjw</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Akizawa, Norikatsu</creator><creator>Ishikawa, Akira</creator><creator>Kogiso, Tetsu</creator><general>GEOCHEMICAL SOCIETY OF JAPAN</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2020</creationdate><title>A simple determination of whole-rock major- and trace-element composition for peridotite by micro-XRF spectrometer and ICP-MS using fused-glass bead</title><author>Akizawa, Norikatsu ; Ishikawa, Akira ; Kogiso, Tetsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a561t-e87dbb5faec32d15f6000f1fae49a24006f12c88955019cb27bca7138882a9a43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>acid digestion</topic><topic>lithium tetraborate glass</topic><topic>mantle xenolith</topic><topic>Tahiti-Moorea islands</topic><topic>whole-rock composition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Akizawa, Norikatsu</creatorcontrib><creatorcontrib>Ishikawa, Akira</creatorcontrib><creatorcontrib>Kogiso, Tetsu</creatorcontrib><collection>CrossRef</collection><jtitle>GEOCHEMICAL JOURNAL</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Akizawa, Norikatsu</au><au>Ishikawa, Akira</au><au>Kogiso, Tetsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A simple determination of whole-rock major- and trace-element composition for peridotite by micro-XRF spectrometer and ICP-MS using fused-glass bead</atitle><jtitle>GEOCHEMICAL JOURNAL</jtitle><addtitle>Geochem. J.</addtitle><date>2020</date><risdate>2020</risdate><volume>54</volume><issue>2</issue><spage>81</spage><epage>90</epage><pages>81-90</pages><issn>0016-7002</issn><eissn>1880-5973</eissn><abstract>A simple analytical procedure for determination of whole-rock major- and trace-element composition by micro-X-ray fluorescence (μXRF) spectrometer and inductively coupled plasma-mass spectrometer (ICP-MS) using fused-glass bead (sample + lithium tetraborate) is presented. In the case of peridotites, chromian spinel (Cr-spinel) is one of the minerals resistant to acids and interferes with accurate and reproducible determination of whole-rock composition. Such resistant minerals were not observed in the fused-glass beads prepared here, suggesting complete digestion of the samples including Cr-spinels. The μXRF spectrometer was employed to determine SiO2, MgO, and total Fe2O3 contents with the fused-glass beads. They were subsequently dissolved into a nitric acid solution to analyze thirty seven elements, Na, Al, P, K, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Rb, Sr, Y, Zr, Nb, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, Pb, Th, and U with sector magnetic field ICP-MS (ICP-SFMS) and Q-pole mass filter ICP-MS (ICP-QMS). The analytical procedures were optimized and evaluated with geological reference materials of JP-1 and BIR-1a, and applied to various mantle xenoliths (lherzolite, harzburgite, dunite, wehrlite, olivine clinopyroxenite, and orthopyroxenite) from Tahiti and Moorea islands (Society Archipelago). Since only fused-glass beads are required as an analytical target to determine whole-rock major- and trace-element compositions, the sample amount consumed through the series of analytical procedure can be constrained to a minute amount (e.g., &lt;0.4 g). The analytical procedures presented here are considered appropriate for tiny and/or precious samples, such as mantle xenoliths and rocks collected by dredging, diving, and drilling from the world’s ocean basins.</abstract><pub>GEOCHEMICAL SOCIETY OF JAPAN</pub><doi>10.2343/geochemj.2.0587</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0016-7002
ispartof GEOCHEMICAL JOURNAL, 2020, Vol.54(2), pp.81-90
issn 0016-7002
1880-5973
language eng
recordid cdi_crossref_primary_10_2343_geochemj_2_0587
source Free Full-Text Journals in Chemistry
subjects acid digestion
lithium tetraborate glass
mantle xenolith
Tahiti-Moorea islands
whole-rock composition
title A simple determination of whole-rock major- and trace-element composition for peridotite by micro-XRF spectrometer and ICP-MS using fused-glass bead
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T09%3A46%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-jstage_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20simple%20determination%20of%20whole-rock%20major-%20and%20trace-element%20composition%20for%20peridotite%20by%20micro-XRF%20spectrometer%20and%20ICP-MS%20using%20fused-glass%20bead&rft.jtitle=GEOCHEMICAL%20JOURNAL&rft.au=Akizawa,%20Norikatsu&rft.date=2020&rft.volume=54&rft.issue=2&rft.spage=81&rft.epage=90&rft.pages=81-90&rft.issn=0016-7002&rft.eissn=1880-5973&rft_id=info:doi/10.2343/geochemj.2.0587&rft_dat=%3Cjstage_cross%3Earticle_geochemj_54_2_54_2_0587_article_char_en%3C/jstage_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a561t-e87dbb5faec32d15f6000f1fae49a24006f12c88955019cb27bca7138882a9a43%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true