Role of thermoxidation and depolymerisation in the ageing of systems paper/gum arabic/historical ink

• Published in: Chemical papers 2014-04, Vol.68 (4), p.564-574
• Main Authors: Peller, András, Reháková, Milena, Ciglanská, Michaela, Šimon, Peter
• Format: Article
• Language: English
• Subjects: accelerated ageing; Biochemistry; Biotechnology; cellulose; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; depolymerisation; Industrial Chemistry/Chemical Engineering; ink stability; Materials Science; Medicinal Chemistry; non-Arrhenian temperature function; Original Paper; thermoxidation
• ISSN: 0366-6352; 1336-9075; 1336-9075
• DOI: 10.2478/s11696-013-0470-1

The aim of this study was to assess the role and proportional representation of depolymerisation and thermoxidation reaction paths in the systems paper/gum arabic (GA)/historical ink during various accelerated ageing methods. The historical inks under study are iron-gall, bistre, and sepia. The results indicate that thermoxidation represents only a minor reaction path in the ageing of paper/GA/ink systems except for the iron-gall ink and the light-thermal method of accelerated ageing. The iron-gall ink accelerates both reaction paths of ageing, i.e. thermoxidation and depolymerisation; in this case, thermoxidation might become the prevailing degradation reaction path. For the sepia ink, an anti-depolymerisation stabilising effect in thermal methods of ageing has been detected. Considering the thermoxidation reaction path, the results even suggest that a compound preventing thermoxidation is formed during the thermally accelerated ageing in air and in 100 mg L −1 of NO 2 . In the light-thermal ageing, the most stable sample is the Whatman paper (W)/GA/bistre ink.