Synthesis and the Crystal Structure of a Copper(II) Complex Dervied from Novel Tridentate Ligand: An Unexpected One

A novel tridentate ligand C 5 H 4 NCONHCOC 5 H 4 N (HL) has been formed by Cannizzaro type reaction of pyridine-2-carboxaldehyde and NaNCO in the presence of copper metal ion and its mononuclear distorted square pyramidal complex [Cu(L)(NCO)(H 2 O)], 1 has been synthesised and characterised.

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Bibliographic Details
Published in:Journal of chemical research 2002-10, Vol.2002 (10), p.496-499
Main Authors: Dey, Subrata Kumar, Choudhury, Chirantan Roy, Dey, Sankar Prasad, Dey, Dilip Kumar, Mondal, Nijhuma, Mahalli, S. Ozra Ghodsi, Malik, K.M. Abdul, Mitra, Samiran
Format: Article
Language:English
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Summary:A novel tridentate ligand C 5 H 4 NCONHCOC 5 H 4 N (HL) has been formed by Cannizzaro type reaction of pyridine-2-carboxaldehyde and NaNCO in the presence of copper metal ion and its mononuclear distorted square pyramidal complex [Cu(L)(NCO)(H 2 O)], 1 has been synthesised and characterised.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823402103170510