GaI 3 Catalysed Nucleophilic Addition of Allyltrimethylsilane to Aldehydes

In dichloromethane, the nucleophilic addition of allyltrimethylsilane to aldehydes to give the corresponding homoallyl alcohols in good to excellent yields was catalysed effectively by gallium triiodide which was generated in situ by the reaction of gallium metal and iodine.

Saved in:
Bibliographic Details
Published in:Journal of chemical research 2004-03, Vol.2004 (3), p.216-217
Main Authors: Sun, Peipei, Xian, Yufang, Xiao, Yaping
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In dichloromethane, the nucleophilic addition of allyltrimethylsilane to aldehydes to give the corresponding homoallyl alcohols in good to excellent yields was catalysed effectively by gallium triiodide which was generated in situ by the reaction of gallium metal and iodine.
ISSN:1747-5198
2047-6507
DOI:10.3184/0308234041640627