REDOX BEHAVIOUR OF ANHYDROUS TRANSITION METAL PHOSPHATES

Phase equilibria in ternary systems M/P/O, oxygen co-existence pressures in such systems, stabilisation of metals in rather low oxidation states and eventually electrical and optical charge transfer properties of phosphates are discussed for representative examples from our recent research. The obse...

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Bibliographic Details
Published in:Phosphorus Research Bulletin 2005, Vol.19, pp.25-29
Main Authors: GLAUM, R., DROSS, T., BLUM, M., LITTERSCHEID, C., THAUERN, H.
Format: Article
Language:English
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Summary:Phase equilibria in ternary systems M/P/O, oxygen co-existence pressures in such systems, stabilisation of metals in rather low oxidation states and eventually electrical and optical charge transfer properties of phosphates are discussed for representative examples from our recent research. The observations are summarized with respect to the redox behaviour of anhydrous phosphates.
ISSN:0918-4783
1882-2363
DOI:10.3363/prb1992.19.0_25