THERMAL DECOMPOSITION AND MASS SPECTRUM OF N, N', N'', N''', N''''-PENTAPHENYLIMINOIMIDODIPHOSPHORAMIDE

The thermal decomposition and mass spectrum of N, N', N'', INT''', N'''-pentaphenyliminoimidodiphosphoramide (1) were investigated. It was indicated that 1 decomposed by heating to form mainly N, N', N''-triphenylphosphoric triamide (2) and...

Full description

Saved in:
Bibliographic Details
Published in:Phosphorus Research Bulletin 1995, Vol.5, pp.173-178
Main Authors: FUKUSHIMA, KAZUHIKO, ONO, SHIN, YOSHIMURA, TOSHIAKI, MORITA, HIROYUKI, TSUKURIMICHI, EIICHI, SHIMASAKI, CHOICHIRO
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The thermal decomposition and mass spectrum of N, N', N'', INT''', N'''-pentaphenyliminoimidodiphosphoramide (1) were investigated. It was indicated that 1 decomposed by heating to form mainly N, N', N''-triphenylphosphoric triamide (2) and 2, 2, 4, 4, 6, 6-hexahydro-2, 2, 4, 4, 6, 6-hexakis (phenylamino)-1, 3, 5, 2, 4, 6-triazatriphosphorine (3), and in the mass spectroscopy of 1, the elimination of a phenylamino radical and/or an aniline from the molecular ion and the formation of 2 were observed.
ISSN:0918-4783
1882-2363
DOI:10.3363/prb1992.5.0_173