Vacancy- and interstitial-mediated self-diffusion coefficients determined from the analysis of observed self-diffusion coefficients in silicon crystals

We clarify the mechanisms of self-diffusion mediated by both vacancies and interstitials in silicon crystals. Südkamp and Bracht published carefully measured self-diffusion data for silicon and determined the vacancy-mediated diffusion coefficients from the difference between their new data and prev...

Full description

Saved in:
Bibliographic Details
Published in:Japanese Journal of Applied Physics 2020-04, Vol.59 (4), p.45505
Main Authors: Suezawa, Masashi, Iijima, Yoshiaki, Yonenaga, Ichiro
Format: Article
Language:English
Subjects:
activation energy
interstitial
self-diffusion
silicon
vacancy
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We clarify the mechanisms of self-diffusion mediated by both vacancies and interstitials in silicon crystals. Südkamp and Bracht published carefully measured self-diffusion data for silicon and determined the vacancy-mediated diffusion coefficients from the difference between their new data and previous data of metal diffusion under consideration of a correlation factor. Instead, we analyzed their data using the vacancy properties: the formation energy was obtained from quenching experiments of silicon crystals in a hydrogen atmosphere, and the migration energy determined from low-temperature electron irradiation. The self-diffusion coefficient is given by the sum of the diffusion coefficients of the vacancy mechanism, 0.90 exp (−4.30 eV/kBT), and the interstitial mechanism, 6.9 × 102 exp (−4.8 eV/kBT) cm2 s−1.
ISSN:0021-4922
1347-4065
DOI:10.35848/1347-4065/ab7d7f