Application of CoFe2O4@CuS magnetic nanocomposite as a novel adsorbent for removal of Penicillin G from aqueous solutions: Isotherm, kinetic and thermodynamic study

• Published in: Desalination and water treatment 2019-04, Vol.148, p.363-373
• Main Authors: Kamranifar, Mohammad, Allahresani, Ali, Naghizadeh, Ali
• Format: Article
• Language: English
• Subjects: Isotherm; Kinetic; Magnetic nanocomposite; Penicillin G; Thermodynamic
• ISSN: 1944-3986
• DOI: 10.5004/dwt.2019.23966

In this study, CoFe2O4@CuS magnetic nanocomposite was synthesized and used to removal of Penicillin G (PG) from aqueous solutions. The synthesized magnetic nanocomposite were characterized with scanning electron microscopy (SEM), transmission electron microscopy (TEM), fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), vibrating-sample magnetometer (VSM).Also, the impact of major parameters including pH (3–11), adsorbent dosage (0.2–0.8 g/L), PG concentration (10–100 mg/L), contact time (10–120 min) and temperature (283–313 K) were studied. Finally, isotherm, kinetic and thermodynamics of adsorption process of PG onto CoFe2O4@CuS magnetic nanocomposite were investigated. According to the results of this study, CoFe2O4@CuS magnetic nanocomposite used to adsorption of PG in optimum condition has maximum adsorption capacity of 41 mg/g (optimum condition pH = 5, adsorbent dosage: 0.2 g/L, PG concentration: 100 mg/L, contact time: 40 min and temperature 313 K). Results of thermodynamic study showed that all the values of ∆G, ∆H and ∆S were positive. Also isotherm study showed that adsorption of PG on CoFe2O4@CuS magnetic nanocomposite better compatibility with Langmuir and then Tem- kin, Freudlich and Dubinin-Radushkevich models. Also, by comparing the kinetics of the adsorption process, it was determined that the pseudo-second order kinetics was able to provide a better description of the kinetics of adsorption.