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Multifunctional Quaternary Phosphorus/Bromoargentate Hybrids: The Achievement of Greenish Blue Luminescence, Repeatable Photocurrent Responses and Durable Antimicrobial Activities with Enhanced Water Stability

The realization of multifunction in one bulk material is fascinating for developing a new generation of devices. Quaternary phosphorus salts were seldom utilized as templates in haloargentate systems, and the hybridization of alkyl(triphenyl)phosphonium with halometallate will be a good strategy for...

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Bibliographic Details
Published in:International journal of nanomedicine 2020-01, Vol.15, p.6225-6237
Main Authors: Liu, Jing-Bo, Zhang, Qiao-Jun, Liu, Jian-Zhi, Zhang, Wen-Ting, Li, Yi, Li, Hao-Hong, Chen, Zhi-Rong, Zheng, Da-Li
Format: Article
Language:English
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Summary:The realization of multifunction in one bulk material is fascinating for developing a new generation of devices. Quaternary phosphorus salts were seldom utilized as templates in haloargentate systems, and the hybridization of alkyl(triphenyl)phosphonium with halometallate will be a good strategy for the development of multifunctional material, especially for biological material. Under the template of (triphenyl)phosphonium-based quaternary phosphorus salts with different spacer lengths (n=2, 3, 4), three bromoargentate hybrids were constructed via the solution method, ie, (1,2-DBTPP)(Ag Br ) ( ), {(1,3-DBTPP) (Ag Br )]∙CH CN∙H O} ( ), and {[(1,4-DBTPP)(Ag Br )](CH CN) ∙H O} ( ) (1,2-DBTPP =ethane-1,2-diylbis (triphenyl)phosphonium, 1,3-DBTPP =propane-1,3-diylbis (triphenyl)phosphonium, 1,4-DBTPP =butane-1,4-diylbis (triphenyl)phosphonium)). The (Ag Br ) chain in is a new type of 1-D bromoargentate chain constructed from cubane-like Ag Br nodes, AgBr tetrahedrons and AgBr triangles. Interestingly, by elongating spacer n from 2 to 4, argentophilicity interactions are weakened, and the hydrogen bonds are strengthened. Consequently, their water stabilities and photocurrents are improved, in which the Ag-4d/Br-4p to π* anti-bonding orbital of the quaternary phosphorus transfer is facilitated. Furthermore, the greenish blue emissions can be detected. Finally, high inhabitation rates against and can be observed in and . In all experiments, by elongating the spacer lengths of quaternary phosphorus salts, multifunctions were integrated in the quaternary phosphorus/bromoargentate hybrids, including greenish blue luminescence, repeatable photocurrent responses and durable antimicrobial activities with enhanced water stability. This work could provide a theoretical guide for the design of new biologically multifunctional materials.
ISSN:1178-2013
1176-9114
1178-2013
DOI:10.2147/IJN.S259156