Loading…
Adsorption Kinetics and Isotherms of Cr(VI) Ions in Aqueous Solution by Biochar Derived from Torreya grandis Nutshell
Biochar is thought to be a good adsorption material for the adsorption of heavy metals. In this study, biochar derived from Torreya grandis nutshell was prepared through to be pyrolyzed under oxygen limited conditions in a muffle furnace. The adsorption experiments of Cr(VI) were carried out. Throug...
Saved in:
Published in: | Nature environment and pollution technology 2019-12, Vol.18 (4), p.1375-1380 |
---|---|
Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | Biochar is thought to be a good adsorption material for the adsorption of heavy metals. In this study, biochar derived from Torreya grandis nutshell was prepared through to be pyrolyzed under oxygen limited conditions in a muffle furnace. The adsorption experiments of Cr(VI) were carried out. Through Elemental Analyzer, Specific Surface Area Meter, Scanning Electron Microscopy, Transmission Electron Microscopy and Fourier Transform Infrared Spectroscopy, a fundamental understanding of the physical and chemical properties of biochar was gained. The results showed that it was a smooth sheet and irregular arrangement structure. The elements of C, H, O and N of biochar are 45.21%, 5.18%, 46.16% and 3.45% respectively. BET specific surface area of biochar is 42.24 m2/g. A lot of oxygen-containing functional groups (-OH, COO-, - C-OH and so on ) appeared on the surface of biochar. It can be described by the pseudo-second order kinetic rate model and Langmuir isotherm model. The adsorption process is a monolayer chemical process. The adsorption mechanism of biochar on heavy metal Cr(VI) contains the electrostatic attraction between biochar and Cr2O72-, HCrO4- and CrO42- ions in aqueous solution and complexation reaction of oxygen-containing functional groups (- OH, -COOH and so on) and Cr2O72-, HCrO4- and CrO42- ions on the surface of biochar. |
---|---|
ISSN: | 0972-6268 2395-3454 |