(3-Ammonio-2,2-dimethyl-propyl)carbamate Dihydrate

(3-Ammonio-2,2-dimethylpropyl)carbamate dihydrate was synthesised. The title compound was characterised by single crystal X-ray diffraction and IR-/Raman-spectroscopy. It has been demonstrated that a mixture of dilute acetic acid and 2,2-dimethyl-1,3-diaminopropane is able to capture CO2 spontaneous...

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Bibliographic Details
Published in:MolBank 2018-09, Vol.2018 (3), p.M1015
Main Authors: Heimgert, Jaqueline, Neumann, Dennis, Reiss, Guido
Format: Article
Language:English
Subjects:
Acetic acid
Amino acids
carbamate
Carbon dioxide
Chemical bonds
Climate change
CO2 absorption
Crystal structure
hydrogen bond
Hydrogen bonds
Infrared spectroscopy
Iodine
Porous materials
Single crystals
Spectrum analysis
Vibration
X ray spectra
X-ray crystallography
X-ray diffraction
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Summary:(3-Ammonio-2,2-dimethylpropyl)carbamate dihydrate was synthesised. The title compound was characterised by single crystal X-ray diffraction and IR-/Raman-spectroscopy. It has been demonstrated that a mixture of dilute acetic acid and 2,2-dimethyl-1,3-diaminopropane is able to capture CO2 spontaneously from the atmosphere. An intramolecular hydrogen bond stabilises the conformation of the ylide-type title molecule. Intermolecular hydrogen bonds between all moieties connect them to a strand-type chain structure.
ISSN:1422-8599
1422-8599
DOI:10.3390/M1015