Single-Step Fabrication and Characterization of Nanoscale Cu Thinfilms for Optoelectronic Applications

• Published in: Crystals (Basel) 2022-01, Vol.12 (1), p.62
• Main Authors: Alrobei, Hussein, Maqbool, Adnan, Hussain, Muhammad Asif, Malik, Rizwan Ahmed, Karim, Muhammad Ramzan Abdul, AlBaijan, Ibrahim, Hafiz, Azeem, Latif, Muhammad
• Format: Article
• Language: English
• Subjects: Coated particles; Copper; Crystallites; Electric potential; Electrical properties; Electrical resistivity; Experiments; flexible substrate; functional coatings; Glass substrates; Light; Metal coatings; Nanomaterials; Nanoparticles; Nanostructure; nanostructured coating; Nanostructured materials; Optical properties; Optics; Optoelectronic devices; Photovoltaic cells; Quantum dots; Solar cells; Thickness; Thin films; Voltage
• ISSN: 2073-4352; 2073-4352
• DOI: 10.3390/cryst12010062

Nanostructured materials with optical transmittance with sufficient electrical conductivity are feasible for the transparent electrical devices and optoelectronic applications. Copper (Cu) possesses inherent superior electrical conductivity. Cu thin films on glass substrates provide the basic design understanding of the transparent electrodes for humidity sensors and solar cells applications. To understand the fundamental fabrication and electrical properties, a single-step facile fabrication approach was applied for Cu nanofilms through the DC sputtering method. Correlation of thickness of Cu nanofilms with optical and electrical properties was established. Parameters such as current, voltage, vacuum pressure, and time of coating were varied to develop different thickness of metal coating. Under optimized conditions of 10−1 torr vacuum, 1.45 KV voltage, and 4–6 min coating time, a conductive path is successfully established. A 1 min coated sample demonstrated resistance of 4000 ohm and conductance of a 6 min coated sample was raised to 56 m-mho. A higher surge of voltage assisted the production of relatively thick and uniform coatings with the crystallite size of 12 nm. The average coating thickness of 19.8 nm and roughness of 4.5 nm was obtained for a 5 min coated sample through AFM analysis. Further, it was observed that uniform nanostructured coating is essential to establish a mean free path of coated particles.