Recyclable Ir Nanoparticles for the Catalytic Hydrogenation of Biomass-Derived Carbonyl Compounds

The valorisation of biomass-derived platform chemicals via catalytic hydrogenation is an eco-friendly tool which allows us to recover bio-based building blocks and produce fine chemicals with high industrial appeal. In the present study, a novel surfactant-type triazolyl-thioether ligand was prepare...

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Published in:Catalysts 2021-08, Vol.11 (8), p.914
Main Authors: Sole, Roberto, Buranello, Chiara, Bardella, Noemi, Di Michele, Alessandro, Paganelli, Stefano, Beghetto, Valentina
Format: Article
Language:English
Subjects:
Alcohol
Biomass
Carbonyl compounds
Carbonyls
Catalysis
Catalysts
Catalytic activity
Chemical reactions
Cinnamaldehyde
Citral
click chemistry
Dichlorides
Experiments
Fine chemicals
Green chemistry
Hydrogenation
Hydroxymethylfurfural
Iridium
Levulinic acid
Ligands
Liquid-liquid extraction
Nanoparticles
platform chemicals
recyclable
Recycling
Solvents
Surfactants
Vanillin
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container_issue 8
container_start_page 914
container_title Catalysts
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creator Sole, Roberto
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Beghetto, Valentina
description The valorisation of biomass-derived platform chemicals via catalytic hydrogenation is an eco-friendly tool which allows us to recover bio-based building blocks and produce fine chemicals with high industrial appeal. In the present study, a novel surfactant-type triazolyl-thioether ligand was prepared, showing excellent catalytic activity in the presence of bis(1,5-cyclooctadiene)diiridium(I) dichloride [Ir(COD)Cl]2 for the hydrogenation of furfural, cinnamaldehyde, levulinic acid, 5-hydroxymethylfurfural, vanillin, and citral. Easy recovery by liquid/liquid extraction allowed us to recover the catalyst, which could then be efficiently recycled up to 11 times for the hydrogenation of furfural. In-depth analysis revealed the formation of spherical structures with metal nanoparticles as big as 2–6 nm surrounded by the anionic ligand, preventing iridium nanoparticle degradation.
doi_str_mv 10.3390/catal11080914
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ispartof Catalysts, 2021-08, Vol.11 (8), p.914
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source Publicly Available Content Database
subjects Alcohol
Biomass
Carbonyl compounds
Carbonyls
Catalysis
Catalysts
Catalytic activity
Chemical reactions
Cinnamaldehyde
Citral
click chemistry
Dichlorides
Experiments
Fine chemicals
Green chemistry
Hydrogenation
Hydroxymethylfurfural
Iridium
Levulinic acid
Ligands
Liquid-liquid extraction
Nanoparticles
platform chemicals
recyclable
Recycling
Solvents
Surfactants
Vanillin
title Recyclable Ir Nanoparticles for the Catalytic Hydrogenation of Biomass-Derived Carbonyl Compounds
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