Microstructural Study of IF-WS2 Failure Modes

• Published in: Inorganics 2014-09, Vol.2 (3), p.377-395
• Main Authors: Cook, Jamie, Rhyans, Steven, Roncase, Lou, Hobson, Garth, Luhrs, Claudia
• Format: Article
• Language: English
• Subjects: Fracture mechanics; fracture mechanism; IF-WS2; Microstructure; Nanoparticles; shock absorbing structures; Studies
• ISSN: 2304-6740; 2304-6740
• DOI: 10.3390/inorganics2030377

This manuscript summarizes the failure mechanisms found in inorganic fullerene-type tungsten disulfide (IF-WS2) nanoparticles treated with diverse pressure loading methods. The approaches utilized to induce failure included: the use of an ultrasonic horn, the buildup of high pressures inside a shock tube which created a shock wave that propagated and impinged in the sample, and impact with military rounds. After treatment, samples were characterized using electron microscopy, powder X-ray diffraction, energy dispersive X-ray spectroscopy, and surface area analysis. The microstructural changes observed in the IF-WS2 particulates as a consequence of the treatments could be categorized in two distinct fracture modes. The most commonly observed was the formation of a crack at the particles surface followed by a phase transformation from the 3D cage-like structures into the 2D layered polymorphs, with subsequent agglomeration of the plate-like sheets to produce larger particle sizes. The secondary mechanism identified was the incipient delamination of IF-WS2. We encountered evidence that the IF-WS2 structure collapse initiated in all cases at the edges and vertices of the polyhedral particles, which acted as stress concentrators, independent of the load application mode or its duration.