Clay‐Loaded Starch‐Grafted Chitosan as Environmentally Controlled Release Material for Atrazine

Herein, controlled‐release material for atrazine (ATZ) herbicide was formulated using different ratios of kaoline (Kao) clay‐loaded starch (ST)‐grafted chitosan (CHT). The materials were characterized by FTIR, SEM and EDX. The ATZ‐release kinetics were studied using the zero‐order, first‐order and K...

Full description

Saved in:
Bibliographic Details
Published in:Applied and environmental soil science 2024-01, Vol.2024 (1)
Main Authors: Jindor, Norbert J, Amenorfe, Leticia P, Kangmennaa, Ahmed, Forkuo, Richard B, Okyere, Harry, Boadi, Nathaniel O, Opoku, Francis
Format: Article
Language:English
Subjects:
Agricultural production
Analysis
Atrazine
Biodegradation
Biopolymers
Chitosan
Clay
Conductivity
Controlled release
Heat resistance
Herbicides
Hydrogels
Microwaves
Particle size
Pesticides
Soils
Starch
Test methods
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c1980-b51ea07cca3a4fa864d6f1d6766b3fcac036d091009e968a63f03db9f9e1978a3
container_end_page
container_issue 1
container_start_page
container_title Applied and environmental soil science
container_volume 2024
creator Jindor, Norbert J
Amenorfe, Leticia P
Kangmennaa, Ahmed
Forkuo, Richard B
Okyere, Harry
Boadi, Nathaniel O
Opoku, Francis
description Herein, controlled‐release material for atrazine (ATZ) herbicide was formulated using different ratios of kaoline (Kao) clay‐loaded starch (ST)‐grafted chitosan (CHT). The materials were characterized by FTIR, SEM and EDX. The ATZ‐release kinetics were studied using the zero‐order, first‐order and Korsmeyer–Peppas models. The percentage release of the active ATZ in the ST‐g‐CHT/Kao/ATZ, Kao/ATZ and bare ATZ were 9, 57 and 99 within 96 h, respectively. The Korsmeyer–Peppas model better described the release of active ATZ from the ST‐g‐CHT/Kao/ATZ system ( R 2 = 0.999), which delineates a non‐Fickian diffusion mechanism that the release was controlled by diffusion and dissolution.
doi_str_mv 10.1155/aess/9985874
format article
fullrecord <record><control><sourceid>gale_doaj_</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_04d87a0f708c4290b3d40b1a878497ab</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A819297268</galeid><doaj_id>oai_doaj_org_article_04d87a0f708c4290b3d40b1a878497ab</doaj_id><sourcerecordid>A819297268</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1980-b51ea07cca3a4fa864d6f1d6766b3fcac036d091009e968a63f03db9f9e1978a3</originalsourceid><addsrcrecordid>eNptUctqHDEQHEICcZzc8gEDuWbt1mpGj-MyOI5hjcFOzqJHD1uLVnIkObA-5RPyjfkSy1njEDB96O6iuqimuu4jgSNCxvEYbSnHUopR8OFVd0CY4AvO-Pj6eWb8bfeulA0Ak-PIDjo9Bdz9-fV7ndBY019VzPqm7acZXW3AdONrKhh7LP1J_OlzilsbK4aw66cUa04hNNqlDRaL7c-x2uwx9C7lflUz3vto33dvHIZiPzz1w-77l5Nv09fF-uL0bFqtF5pIAYt5JBaBa40UB4eCDYY5YlhzPVOnUQNlBiQBkFYygYw6oGaWTloiuUB62J3tdU3CjbrNfot5pxJ69RdI-Vphrl4Hq2AwgiM4DkIPSwkzNQPMBAUXg-Q4N61Pe63bnH7c2VLVJt3l2OwrSoYliFEy-Me6xibqo0vtZb31RauVIHIp-ZKJxjp6gdXK2K3XKVrnG_7fwef9gc6plGzd8zME1GPS6jFp9ZQ0fQDBTZy1</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3142085960</pqid></control><display><type>article</type><title>Clay‐Loaded Starch‐Grafted Chitosan as Environmentally Controlled Release Material for Atrazine</title><source>Publicly Available Content (ProQuest)</source><source>Wiley Open Access</source><creator>Jindor, Norbert J ; Amenorfe, Leticia P ; Kangmennaa, Ahmed ; Forkuo, Richard B ; Okyere, Harry ; Boadi, Nathaniel O ; Opoku, Francis</creator><contributor>Koo, Bon-Jun ; Bon-Jun Koo</contributor><creatorcontrib>Jindor, Norbert J ; Amenorfe, Leticia P ; Kangmennaa, Ahmed ; Forkuo, Richard B ; Okyere, Harry ; Boadi, Nathaniel O ; Opoku, Francis ; Koo, Bon-Jun ; Bon-Jun Koo</creatorcontrib><description>Herein, controlled‐release material for atrazine (ATZ) herbicide was formulated using different ratios of kaoline (Kao) clay‐loaded starch (ST)‐grafted chitosan (CHT). The materials were characterized by FTIR, SEM and EDX. The ATZ‐release kinetics were studied using the zero‐order, first‐order and Korsmeyer–Peppas models. The percentage release of the active ATZ in the ST‐g‐CHT/Kao/ATZ, Kao/ATZ and bare ATZ were 9, 57 and 99 within 96 h, respectively. The Korsmeyer–Peppas model better described the release of active ATZ from the ST‐g‐CHT/Kao/ATZ system ( R 2 = 0.999), which delineates a non‐Fickian diffusion mechanism that the release was controlled by diffusion and dissolution.</description><identifier>ISSN: 1687-7667</identifier><identifier>EISSN: 1687-7675</identifier><identifier>DOI: 10.1155/aess/9985874</identifier><language>eng</language><publisher>New York: John Wiley &amp; Sons, Inc</publisher><subject>Agricultural production ; Analysis ; Atrazine ; Biodegradation ; Biopolymers ; Chitosan ; Clay ; Conductivity ; Controlled release ; Heat resistance ; Herbicides ; Hydrogels ; Microwaves ; Particle size ; Pesticides ; Soils ; Starch ; Test methods</subject><ispartof>Applied and environmental soil science, 2024-01, Vol.2024 (1)</ispartof><rights>COPYRIGHT 2024 John Wiley &amp; Sons, Inc.</rights><rights>Copyright © 2024 Norbert J. Jindor et al. This is an open access article distributed under the Creative Commons Attribution License (the “License”), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. https://creativecommons.org/licenses/by/4.0</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1980-b51ea07cca3a4fa864d6f1d6766b3fcac036d091009e968a63f03db9f9e1978a3</cites><orcidid>0000-0003-4198-554X ; 0000-0003-2673-7011</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/3142085960/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/3142085960?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,25753,27924,27925,37012,44590,75126</link.rule.ids></links><search><contributor>Koo, Bon-Jun</contributor><contributor>Bon-Jun Koo</contributor><creatorcontrib>Jindor, Norbert J</creatorcontrib><creatorcontrib>Amenorfe, Leticia P</creatorcontrib><creatorcontrib>Kangmennaa, Ahmed</creatorcontrib><creatorcontrib>Forkuo, Richard B</creatorcontrib><creatorcontrib>Okyere, Harry</creatorcontrib><creatorcontrib>Boadi, Nathaniel O</creatorcontrib><creatorcontrib>Opoku, Francis</creatorcontrib><title>Clay‐Loaded Starch‐Grafted Chitosan as Environmentally Controlled Release Material for Atrazine</title><title>Applied and environmental soil science</title><description>Herein, controlled‐release material for atrazine (ATZ) herbicide was formulated using different ratios of kaoline (Kao) clay‐loaded starch (ST)‐grafted chitosan (CHT). The materials were characterized by FTIR, SEM and EDX. The ATZ‐release kinetics were studied using the zero‐order, first‐order and Korsmeyer–Peppas models. The percentage release of the active ATZ in the ST‐g‐CHT/Kao/ATZ, Kao/ATZ and bare ATZ were 9, 57 and 99 within 96 h, respectively. The Korsmeyer–Peppas model better described the release of active ATZ from the ST‐g‐CHT/Kao/ATZ system ( R 2 = 0.999), which delineates a non‐Fickian diffusion mechanism that the release was controlled by diffusion and dissolution.</description><subject>Agricultural production</subject><subject>Analysis</subject><subject>Atrazine</subject><subject>Biodegradation</subject><subject>Biopolymers</subject><subject>Chitosan</subject><subject>Clay</subject><subject>Conductivity</subject><subject>Controlled release</subject><subject>Heat resistance</subject><subject>Herbicides</subject><subject>Hydrogels</subject><subject>Microwaves</subject><subject>Particle size</subject><subject>Pesticides</subject><subject>Soils</subject><subject>Starch</subject><subject>Test methods</subject><issn>1687-7667</issn><issn>1687-7675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNptUctqHDEQHEICcZzc8gEDuWbt1mpGj-MyOI5hjcFOzqJHD1uLVnIkObA-5RPyjfkSy1njEDB96O6iuqimuu4jgSNCxvEYbSnHUopR8OFVd0CY4AvO-Pj6eWb8bfeulA0Ak-PIDjo9Bdz9-fV7ndBY019VzPqm7acZXW3AdONrKhh7LP1J_OlzilsbK4aw66cUa04hNNqlDRaL7c-x2uwx9C7lflUz3vto33dvHIZiPzz1w-77l5Nv09fF-uL0bFqtF5pIAYt5JBaBa40UB4eCDYY5YlhzPVOnUQNlBiQBkFYygYw6oGaWTloiuUB62J3tdU3CjbrNfot5pxJ69RdI-Vphrl4Hq2AwgiM4DkIPSwkzNQPMBAUXg-Q4N61Pe63bnH7c2VLVJt3l2OwrSoYliFEy-Me6xibqo0vtZb31RauVIHIp-ZKJxjp6gdXK2K3XKVrnG_7fwef9gc6plGzd8zME1GPS6jFp9ZQ0fQDBTZy1</recordid><startdate>20240101</startdate><enddate>20240101</enddate><creator>Jindor, Norbert J</creator><creator>Amenorfe, Leticia P</creator><creator>Kangmennaa, Ahmed</creator><creator>Forkuo, Richard B</creator><creator>Okyere, Harry</creator><creator>Boadi, Nathaniel O</creator><creator>Opoku, Francis</creator><general>John Wiley &amp; Sons, Inc</general><general>Hindawi Limited</general><general>Wiley</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7ST</scope><scope>7X2</scope><scope>8FE</scope><scope>8FG</scope><scope>8FH</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>CWDGH</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M0K</scope><scope>M7S</scope><scope>PATMY</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>PYCSY</scope><scope>SOI</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0003-4198-554X</orcidid><orcidid>https://orcid.org/0000-0003-2673-7011</orcidid></search><sort><creationdate>20240101</creationdate><title>Clay‐Loaded Starch‐Grafted Chitosan as Environmentally Controlled Release Material for Atrazine</title><author>Jindor, Norbert J ; Amenorfe, Leticia P ; Kangmennaa, Ahmed ; Forkuo, Richard B ; Okyere, Harry ; Boadi, Nathaniel O ; Opoku, Francis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1980-b51ea07cca3a4fa864d6f1d6766b3fcac036d091009e968a63f03db9f9e1978a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Agricultural production</topic><topic>Analysis</topic><topic>Atrazine</topic><topic>Biodegradation</topic><topic>Biopolymers</topic><topic>Chitosan</topic><topic>Clay</topic><topic>Conductivity</topic><topic>Controlled release</topic><topic>Heat resistance</topic><topic>Herbicides</topic><topic>Hydrogels</topic><topic>Microwaves</topic><topic>Particle size</topic><topic>Pesticides</topic><topic>Soils</topic><topic>Starch</topic><topic>Test methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jindor, Norbert J</creatorcontrib><creatorcontrib>Amenorfe, Leticia P</creatorcontrib><creatorcontrib>Kangmennaa, Ahmed</creatorcontrib><creatorcontrib>Forkuo, Richard B</creatorcontrib><creatorcontrib>Okyere, Harry</creatorcontrib><creatorcontrib>Boadi, Nathaniel O</creatorcontrib><creatorcontrib>Opoku, Francis</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Environment Abstracts</collection><collection>Agricultural Science Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>Agricultural &amp; Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Middle East &amp; Africa Database</collection><collection>ProQuest Central</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Agriculture Science Database</collection><collection>Engineering Database</collection><collection>Environmental Science Database</collection><collection>Publicly Available Content (ProQuest)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><collection>Environmental Science Collection</collection><collection>Environment Abstracts</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Applied and environmental soil science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jindor, Norbert J</au><au>Amenorfe, Leticia P</au><au>Kangmennaa, Ahmed</au><au>Forkuo, Richard B</au><au>Okyere, Harry</au><au>Boadi, Nathaniel O</au><au>Opoku, Francis</au><au>Koo, Bon-Jun</au><au>Bon-Jun Koo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Clay‐Loaded Starch‐Grafted Chitosan as Environmentally Controlled Release Material for Atrazine</atitle><jtitle>Applied and environmental soil science</jtitle><date>2024-01-01</date><risdate>2024</risdate><volume>2024</volume><issue>1</issue><issn>1687-7667</issn><eissn>1687-7675</eissn><abstract>Herein, controlled‐release material for atrazine (ATZ) herbicide was formulated using different ratios of kaoline (Kao) clay‐loaded starch (ST)‐grafted chitosan (CHT). The materials were characterized by FTIR, SEM and EDX. The ATZ‐release kinetics were studied using the zero‐order, first‐order and Korsmeyer–Peppas models. The percentage release of the active ATZ in the ST‐g‐CHT/Kao/ATZ, Kao/ATZ and bare ATZ were 9, 57 and 99 within 96 h, respectively. The Korsmeyer–Peppas model better described the release of active ATZ from the ST‐g‐CHT/Kao/ATZ system ( R 2 = 0.999), which delineates a non‐Fickian diffusion mechanism that the release was controlled by diffusion and dissolution.</abstract><cop>New York</cop><pub>John Wiley &amp; Sons, Inc</pub><doi>10.1155/aess/9985874</doi><orcidid>https://orcid.org/0000-0003-4198-554X</orcidid><orcidid>https://orcid.org/0000-0003-2673-7011</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1687-7667
ispartof Applied and environmental soil science, 2024-01, Vol.2024 (1)
issn 1687-7667
1687-7675
language eng
recordid cdi_doaj_primary_oai_doaj_org_article_04d87a0f708c4290b3d40b1a878497ab
source Publicly Available Content (ProQuest); Wiley Open Access
subjects Agricultural production
Analysis
Atrazine
Biodegradation
Biopolymers
Chitosan
Clay
Conductivity
Controlled release
Heat resistance
Herbicides
Hydrogels
Microwaves
Particle size
Pesticides
Soils
Starch
Test methods
title Clay‐Loaded Starch‐Grafted Chitosan as Environmentally Controlled Release Material for Atrazine
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T00%3A31%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_doaj_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Clay%E2%80%90Loaded%20Starch%E2%80%90Grafted%20Chitosan%20as%20Environmentally%20Controlled%20Release%20Material%20for%20Atrazine&rft.jtitle=Applied%20and%20environmental%20soil%20science&rft.au=Jindor,%20Norbert%20J&rft.date=2024-01-01&rft.volume=2024&rft.issue=1&rft.issn=1687-7667&rft.eissn=1687-7675&rft_id=info:doi/10.1155/aess/9985874&rft_dat=%3Cgale_doaj_%3EA819297268%3C/gale_doaj_%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1980-b51ea07cca3a4fa864d6f1d6766b3fcac036d091009e968a63f03db9f9e1978a3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=3142085960&rft_id=info:pmid/&rft_galeid=A819297268&rfr_iscdi=true