(E)-2-(4-Chloro-phen-oxy)-N'-(pyridin-4-yl-methyl-idene)acetohydrazide

In the title compound, C14H12ClN3O2, the acyl-hydrazone base [C(=O)-N-N=C] is essentially planar, with an r.m.s. deviation of 0.0095 Å, and makes a dihedral angle of 12.52 (10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers wi...

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Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-01, Vol.69 (Pt 1), p.o28-o28
Main Authors: Rao, Xiao-Jin, Wu, Wen-Shi, Li, Chuan-Hui, Huang, Yu-Min
Format: Article
Language:English
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Organic Papers
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Summary:In the title compound, C14H12ClN3O2, the acyl-hydrazone base [C(=O)-N-N=C] is essentially planar, with an r.m.s. deviation of 0.0095 Å, and makes a dihedral angle of 12.52 (10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers with an R2(2)(8) graph-set motif. The dimers are linked via C-H⋯π interactions forming chains along [101].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812045989