Nitrate-Bridged One-Dimension Coordination Polymer Self-Assembled from a N4O2-Tetraiminodiphenolate Dicopper(II) Macrocyclic Complex

Herein we report on the synthesis and single crystal X-ray structure characterization of [ { Cu2(tidf)(μ-NO3) } ∞]ClO4 (tidf = a Robson type macrocyclic ligand obtained upon condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). The coordination geometry around the copper(II) is square...

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Bibliographic Details
Published in:Journal of chemistry 2015-01, Vol.2015 (2015), p.1-6
Main Authors: Nunes, Fábio Souza, Hörner, Manfredo, Zambiazi, Priscilla J., da Rocha, Julio Cesar
Format: Article
Language:English
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Summary:Herein we report on the synthesis and single crystal X-ray structure characterization of [ { Cu2(tidf)(μ-NO3) } ∞]ClO4 (tidf = a Robson type macrocyclic ligand obtained upon condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane). The coordination geometry around the copper(II) is square-pyramidal and has [Cu2(tidf)]2+ units connected to each other through nitrate bridges extending as a one-dimension coordination polymer. The compound exhibits an extensive supramolecular structure supported by nonclassic hydrogen bonding between C-H⋯ O p e r c h l o r a t e and C-H⋯ O n i t r a t e .
ISSN:2090-9063
2090-9071
DOI:10.1155/2015/870834