Loading…

Electrochemical Characterization of Nanoporous Nickel Oxide Thin Films Spray-Deposited onto Indium-Doped Tin Oxide for Solar Conversion Scopes

Nonstoichiometric nickel oxide ( N i O x ) has been deposited as thin film utilizing indium-doped tin oxide as transparent and electrically conductive substrate. Spray deposition of a suspension of N i O x nanoparticles in alcoholic medium allowed the preparation of uniform N i O x coatings. Sinteri...

Full description

Saved in:
Bibliographic Details
Published in:Advances in condensed matter physics 2015-01, Vol.2015 (2015), p.1-18
Main Authors: Dini, Danilo, Decker, Franco, Dowling, Denis P., Awais, Muhammad
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Nonstoichiometric nickel oxide ( N i O x ) has been deposited as thin film utilizing indium-doped tin oxide as transparent and electrically conductive substrate. Spray deposition of a suspension of N i O x nanoparticles in alcoholic medium allowed the preparation of uniform N i O x coatings. Sintering of the coatings was conducted at temperatures below 500°C for few minutes. This scalable procedure allowed the attainment of N i O x films with mesoporous morphology and reticulated structure. The electrochemical characterization showed that N i O x electrodes possess large surface area (about 1000 times larger than their geometrical area). Due to the openness of the N i O x morphology, the underlying conductive substrate can be contacted by the electrolyte and undergo redox processes within the potential range in which N i O x is electroactive. This requires careful control of the conditions of polarization in order to prevent the simultaneous occurrence of reduction/oxidation processes in both components of the multilayered electrode. The combination of the open structure with optical transparency and elevated electroactivity in organic electrolytes motivated us to analyze the potential of the spray-deposited N i O x films as semiconducting cathodes of dye-sensitized solar cells of p-type when erythrosine B was the sensitizer.
ISSN:1687-8108
1687-8124
DOI:10.1155/2015/186375