Natural Product-Oriented Photo-Induced Denitrogenative Annulations of 1-Alkenylbenzotriazoles

The photo-induced denitrogenative annulations of a variety of 1-alkenylbenzotriazoles were investigated. By judiciously manipulating the structural variations of 1-alkenylbenzotriazoles, two characteristic polycyclic skeletons associated with monoterpene indole alkaloids were constructed through a d...

Full description

Saved in:
Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2023-01, Vol.28 (1), p.363
Main Authors: Wang, Zhiguo, Chen, Yi, Dong, Zhen, Tang, Yefeng
Format: Article
Language:English
Subjects:
1-alkenylbenzotriazole
Alkaloids
Analysis
By products
Controllability
denitrogenative annulation
Health aspects
indole alkaloid
Indole Alkaloids - chemistry
Monoterpenes
Natural products
Nitrogen
photochemical transformation
Photochemistry
retro-Fries rearrangement
Spectrum analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The photo-induced denitrogenative annulations of a variety of 1-alkenylbenzotriazoles were investigated. By judiciously manipulating the structural variations of 1-alkenylbenzotriazoles, two characteristic polycyclic skeletons associated with monoterpene indole alkaloids were constructed through a diverted and controllable manner. The present work not only enriches the photochemistry of 1-alkenylbenzotriazoles, but also offers a unified approach to access skeletally diverse indole alkaloid scaffolds.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules28010363