{4-Chloro- N ′-[(2-oxidonaphthalen-1-yl-κ O )methylidene]benzohydrazidato-κ 2 N ′, O }dimethyltin(IV)

In the title complex, [Sn(CH 3 ) 2 (C 18 H 11 ClN 2 O 2 )], the Sn IV ion is coordinated by two O atoms and an N atom from a 4-chloro- N ′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-12, Vol.69 (12), p.m688-m688
Main Authors: Cui, Jichun, Qiao, Yanling, Wang, Fei
Format: Article
Language:English
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Summary:In the title complex, [Sn(CH 3 ) 2 (C 18 H 11 ClN 2 O 2 )], the Sn IV ion is coordinated by two O atoms and an N atom from a 4-chloro- N ′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (3) and 2.144 (3) Å; Sn—N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent molecules are linked by weak C—H...O hydrogen bonds, forming a chain along the b- axis direction.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813031826