Highly Sensitive Room Temperature H2S Gas Sensor Based on the Nanocomposite of MoS2–ZnCo2O4

• Published in: ACS omega 2023-12, Vol.8 (49), p.47023-47033
• Main Authors: Sadaf, Shama, Zhang, Hongpeng, Chen, Daru, Akhtar, Ali
• Format: Article
• Language: English
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.3c06876

The stacking 2D materials, such as molybdenum disulfide (MoS2), are among the most promising candidates for detecting H2S gas. Herein, we designed a series of novel nanocomposites consisting of MoS2 and ZnCo2O4. These materials were synthesized via a simple hydrothermal method. The microstructure and morphology of nanocomposites were studied by different characteristics such as X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, high-resolution transmission electron microscopy, Brunauer–Emmett–Teller (BET), and X-ray photoelectron spectroscopy. These nanocomposites were used as gas sensors, and the highest response (6.6) toward 10 ppm of H2S was detected by the gas sensor of MZCO-6 (having MoS2 contents 0.060 g) among all other tested sensors. The response value (R a/R g) was almost three times that of pure ZnCo2O4 (R a/R g = 2). In addition, the sensor of MZCO-6 exposed good selectivity, short response/recovery time (12/28 s), long-term stability (28 days), and a low detection limit (0.5 ppm) toward H2S gas at RT. The excellent performance of MZCO-6 may be attributed to some features of MoS2, such as stack structure, higher BET and surface area and active sites, a synergistic effect, etc. This simple fabrication sensor provides a novel idea for detecting H2S gas at RT.