Synthesis, crystal structure, and fungicidal activity of triorganotin(IV) 1-methyl-1H-imidazole-4-carboxylates

Two triorganotin carboxylates of 1-methyl-1 -imidazole-4-carboxylic acid (HL), Cy SnL and C C(CH3) CH SnL, have been prepared by the reaction of the ligand with tricyclohexyltin hydroxide and fenbutatin oxide, respectively. The complexes were characterized by H NMR, infrared, and elemental analysis....

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Bibliographic Details
Published in:Main group metal chemistry 2015-03, Vol.38 (1), p.27-30
Main Authors: Mao, Wutao, Bao, Keyan, Feng, Yuquan, Wang, Qingfeng, Li, Juajuan, Fan, Zhinjin
Format: Article
Language:English
Subjects:
1-methyl-1
1-methyl-1h-imidazole-4-carboxylic acid
Crystal structure
Diffraction
fungicidal activity
Fungicides
imidazole-4-carboxylic acid
Infrared
Ligands
organotin(IV) carboxylates
Oxides
Synthesis
X-rays
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Summary:Two triorganotin carboxylates of 1-methyl-1 -imidazole-4-carboxylic acid (HL), Cy SnL and C C(CH3) CH SnL, have been prepared by the reaction of the ligand with tricyclohexyltin hydroxide and fenbutatin oxide, respectively. The complexes were characterized by H NMR, infrared, and elemental analysis. The molecular structure of complex was determined by using a single-crystal X-ray diffraction analysis. Preliminary bioassay indicated complex exhibiting good and broad-spectrum fungicidal activities.
ISSN:0792-1241
2191-0219
DOI:10.1515/mgmc-2014-0040