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Easy Ligand Activation in the Coordination Sphere of Ru inside the [PW 11 O 39 ] 7- Backbone
Irradiation of the Keggin-type [PW O {Ru(NO)}] ( ) polyoxometalate in CH CN results in rapid NO ligand elimination with the formation of [PW O {Ru (CH CN)}] ( ). This complex offers an easy entry into the Ru-based chemistry of the {PW Ru} complex. Attempts to substitute N for CH CN in the presence o...
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| Published in: | Molecules (Basel, Switzerland) Switzerland), 2020-04, Vol.25 (8), p.1859 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c3389-f5976a0f90c3f906976b8487d773564d8a9ec6f7318281b6f58e9f346d853f083 |
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| cites | cdi_FETCH-LOGICAL-c3389-f5976a0f90c3f906976b8487d773564d8a9ec6f7318281b6f58e9f346d853f083 |
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| container_issue | 8 |
| container_start_page | 1859 |
| container_title | Molecules (Basel, Switzerland) |
| container_volume | 25 |
| creator | Mukhacheva, Anna A Gushchin, Artem L Yanshole, Vadim V Abramov, Pavel A Sokolov, Maksim N |
| description | Irradiation of the Keggin-type [PW
O
{Ru(NO)}]
(
) polyoxometalate in CH
CN results in rapid NO ligand elimination with the formation of [PW
O
{Ru
(CH
CN)}]
(
). This complex offers an easy entry into the Ru-based chemistry of the {PW
Ru} complex. Attempts to substitute N
for CH
CN in the presence of an NaN
excess lead a variety of products: (i) [PW
O
{Ru
(N
)}]
(
); (ii) [PW
O
{Ru
(N
HC-CH
)}]
(
) as a click-reaction product; and (iii) [PW
O
{Ru
(N
)}]
(
). UV-VIS, CV, and HR-ESI-MS techniques were used for the reaction monitoring and characterization of the products. |
| doi_str_mv | 10.3390/molecules25081859 |
| format | article |
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O
{Ru(NO)}]
(
) polyoxometalate in CH
CN results in rapid NO ligand elimination with the formation of [PW
O
{Ru
(CH
CN)}]
(
). This complex offers an easy entry into the Ru-based chemistry of the {PW
Ru} complex. Attempts to substitute N
for CH
CN in the presence of an NaN
excess lead a variety of products: (i) [PW
O
{Ru
(N
)}]
(
); (ii) [PW
O
{Ru
(N
HC-CH
)}]
(
) as a click-reaction product; and (iii) [PW
O
{Ru
(N
)}]
(
). UV-VIS, CV, and HR-ESI-MS techniques were used for the reaction monitoring and characterization of the products.</description><identifier>ISSN: 1420-3049</identifier><identifier>EISSN: 1420-3049</identifier><identifier>DOI: 10.3390/molecules25081859</identifier><identifier>PMID: 32316614</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>azide ; Azides - chemistry ; Carbon ; Coordination Complexes - chemistry ; HR-ESI-MS ; Irradiation ; Ligands ; Molecular Structure ; Oxidation ; Photoelectron Spectroscopy ; polyoxometalate ; Reaction products ; ruthenium ; Ruthenium - chemistry ; Spectrometry, Mass, Electrospray Ionization ; Tungsten Compounds - chemistry</subject><ispartof>Molecules (Basel, Switzerland), 2020-04, Vol.25 (8), p.1859</ispartof><rights>2020. This work is licensed under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2020 by the authors. 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3389-f5976a0f90c3f906976b8487d773564d8a9ec6f7318281b6f58e9f346d853f083</citedby><cites>FETCH-LOGICAL-c3389-f5976a0f90c3f906976b8487d773564d8a9ec6f7318281b6f58e9f346d853f083</cites><orcidid>0000-0001-5648-8402 ; 0000-0003-1512-3049 ; 0000-0003-4479-5100</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2393254104/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2393254104?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32316614$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Mukhacheva, Anna A</creatorcontrib><creatorcontrib>Gushchin, Artem L</creatorcontrib><creatorcontrib>Yanshole, Vadim V</creatorcontrib><creatorcontrib>Abramov, Pavel A</creatorcontrib><creatorcontrib>Sokolov, Maksim N</creatorcontrib><title>Easy Ligand Activation in the Coordination Sphere of Ru inside the [PW 11 O 39 ] 7- Backbone</title><title>Molecules (Basel, Switzerland)</title><addtitle>Molecules</addtitle><description>Irradiation of the Keggin-type [PW
O
{Ru(NO)}]
(
) polyoxometalate in CH
CN results in rapid NO ligand elimination with the formation of [PW
O
{Ru
(CH
CN)}]
(
). This complex offers an easy entry into the Ru-based chemistry of the {PW
Ru} complex. Attempts to substitute N
for CH
CN in the presence of an NaN
excess lead a variety of products: (i) [PW
O
{Ru
(N
)}]
(
); (ii) [PW
O
{Ru
(N
HC-CH
)}]
(
) as a click-reaction product; and (iii) [PW
O
{Ru
(N
)}]
(
). UV-VIS, CV, and HR-ESI-MS techniques were used for the reaction monitoring and characterization of the products.</description><subject>azide</subject><subject>Azides - chemistry</subject><subject>Carbon</subject><subject>Coordination Complexes - chemistry</subject><subject>HR-ESI-MS</subject><subject>Irradiation</subject><subject>Ligands</subject><subject>Molecular Structure</subject><subject>Oxidation</subject><subject>Photoelectron Spectroscopy</subject><subject>polyoxometalate</subject><subject>Reaction products</subject><subject>ruthenium</subject><subject>Ruthenium - chemistry</subject><subject>Spectrometry, Mass, Electrospray Ionization</subject><subject>Tungsten Compounds - chemistry</subject><issn>1420-3049</issn><issn>1420-3049</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><sourceid>DOA</sourceid><recordid>eNplkltrFDEUgAdRbK3-AF8k4Isvo0lOri9CXaoWFipe8EElZDLJbtbZyZrMFPrvjbu1tPqSy8l3PpKT0zRPCX4JoPGrbRq8mwdfKMeKKK7vNceEUdwCZvr-rfVR86iUDcaUMMIfNkdAgQhB2HHz_cyWK7SMKzv26NRN8dJOMY0ojmhae7RIKfdxPMQ-7dY-e5QC-jhXoMTe76FvH74iQtAFAo1-INmiN9b97NLoHzcPgh2Kf3I9nzRf3p59Xrxvlxfvzheny9YBKN0GrqWwOGjsoA6i7jrFlOylBC5Yr6z2TgQJRFFFOhG48joAE73iELCCk-b84O2T3Zhdjlubr0yy0ewDKa-MzVN0gzdESC46woMXkjnNNIAToqeiVqSXQlTX64NrN3db3zs_TtkOd6R3T8a4Nqt0aSSlhBNZBS-uBTn9mn2ZzDYW54fBjj7NxVDQwCUwiSv6_B90k-Y81lLtKcoZwaxS5EC5nErJPtxchmDzpw_Mf31Qc57dfsVNxt-Ph98-iKvP</recordid><startdate>20200417</startdate><enddate>20200417</enddate><creator>Mukhacheva, Anna A</creator><creator>Gushchin, Artem L</creator><creator>Yanshole, Vadim V</creator><creator>Abramov, Pavel A</creator><creator>Sokolov, Maksim N</creator><general>MDPI AG</general><general>MDPI</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0001-5648-8402</orcidid><orcidid>https://orcid.org/0000-0003-1512-3049</orcidid><orcidid>https://orcid.org/0000-0003-4479-5100</orcidid></search><sort><creationdate>20200417</creationdate><title>Easy Ligand Activation in the Coordination Sphere of Ru inside the [PW 11 O 39 ] 7- Backbone</title><author>Mukhacheva, Anna A ; Gushchin, Artem L ; Yanshole, Vadim V ; Abramov, Pavel A ; Sokolov, Maksim N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3389-f5976a0f90c3f906976b8487d773564d8a9ec6f7318281b6f58e9f346d853f083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>azide</topic><topic>Azides - chemistry</topic><topic>Carbon</topic><topic>Coordination Complexes - chemistry</topic><topic>HR-ESI-MS</topic><topic>Irradiation</topic><topic>Ligands</topic><topic>Molecular Structure</topic><topic>Oxidation</topic><topic>Photoelectron Spectroscopy</topic><topic>polyoxometalate</topic><topic>Reaction products</topic><topic>ruthenium</topic><topic>Ruthenium - chemistry</topic><topic>Spectrometry, Mass, Electrospray Ionization</topic><topic>Tungsten Compounds - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mukhacheva, Anna A</creatorcontrib><creatorcontrib>Gushchin, Artem L</creatorcontrib><creatorcontrib>Yanshole, Vadim V</creatorcontrib><creatorcontrib>Abramov, Pavel A</creatorcontrib><creatorcontrib>Sokolov, Maksim N</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>ProQuest - Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Molecules (Basel, Switzerland)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mukhacheva, Anna A</au><au>Gushchin, Artem L</au><au>Yanshole, Vadim V</au><au>Abramov, Pavel A</au><au>Sokolov, Maksim N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Easy Ligand Activation in the Coordination Sphere of Ru inside the [PW 11 O 39 ] 7- Backbone</atitle><jtitle>Molecules (Basel, Switzerland)</jtitle><addtitle>Molecules</addtitle><date>2020-04-17</date><risdate>2020</risdate><volume>25</volume><issue>8</issue><spage>1859</spage><pages>1859-</pages><issn>1420-3049</issn><eissn>1420-3049</eissn><abstract>Irradiation of the Keggin-type [PW
O
{Ru(NO)}]
(
) polyoxometalate in CH
CN results in rapid NO ligand elimination with the formation of [PW
O
{Ru
(CH
CN)}]
(
). This complex offers an easy entry into the Ru-based chemistry of the {PW
Ru} complex. Attempts to substitute N
for CH
CN in the presence of an NaN
excess lead a variety of products: (i) [PW
O
{Ru
(N
)}]
(
); (ii) [PW
O
{Ru
(N
HC-CH
)}]
(
) as a click-reaction product; and (iii) [PW
O
{Ru
(N
)}]
(
). UV-VIS, CV, and HR-ESI-MS techniques were used for the reaction monitoring and characterization of the products.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>32316614</pmid><doi>10.3390/molecules25081859</doi><orcidid>https://orcid.org/0000-0001-5648-8402</orcidid><orcidid>https://orcid.org/0000-0003-1512-3049</orcidid><orcidid>https://orcid.org/0000-0003-4479-5100</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1420-3049 |
| ispartof | Molecules (Basel, Switzerland), 2020-04, Vol.25 (8), p.1859 |
| issn | 1420-3049 1420-3049 |
| language | eng |
| recordid | cdi_doaj_primary_oai_doaj_org_article_16756b15fe674c94933c66d26231d766 |
| source | Open Access: PubMed Central; ProQuest - Publicly Available Content Database |
| subjects | azide Azides - chemistry Carbon Coordination Complexes - chemistry HR-ESI-MS Irradiation Ligands Molecular Structure Oxidation Photoelectron Spectroscopy polyoxometalate Reaction products ruthenium Ruthenium - chemistry Spectrometry, Mass, Electrospray Ionization Tungsten Compounds - chemistry |
| title | Easy Ligand Activation in the Coordination Sphere of Ru inside the [PW 11 O 39 ] 7- Backbone |
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