Porous Hydrogen-Bonded Organic Frameworks

Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination cen...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2017-02, Vol.22 (2), p.266
Main Authors: Han, Yi-Fei, Yuan, Ying-Xue, Wang, Hong-Bo
Format: Article
Language:English
Subjects:
Chemistry, Organic
Hydrogen - chemistry
Hydrogen Bonding
hydrogen bonds
Models, Chemical
Models, Molecular
Organic Chemistry Phenomena
organic porous frameworks
Review
supramolecular self-assembly
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Summary:Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination centers and organic linkers. Compared to MOFs, porous hydrogen-bonded organic frameworks (HOFs) are readily purified and recovered via simple recrystallization. However, due to lacking of sufficiently ability to orientate self-aggregation of building motifs in predictable manners, rational design and preparation of porous HOFs are still challenging. Herein, we summarize recent developments about porous HOFs and attempt to gain deeper insights into the design strategies of basic building motifs.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules22020266