1-Ferrocenyl-3-(4-methyl-anilino)propan-1-one

In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo-penta-dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compa...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-02, Vol.68 (Pt 2), p.m230-m230
Main Authors: Leka, Zorica, Novaković, Sladjana B, Stevanović, Dragana, Bogdanović, Goran A, Vukićević, Rastko D
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo-penta-dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229]. The molecules are connected into centro-symmetric dimers via N-H⋯O hydrogen bonds. In addition, C-H⋯O and C-H⋯N contacts stabilize the crystal packing.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812003509