Synthesis, Structure and Antioxidant Activity of Cyclohexene-Fused Selenuranes and Related Derivatives

Synthesis, structure and antioxidant activity of new cyclohexene-fused spiroselenuranes and a spirotellurane is reported. Oxidation reactions of bis(o-formylcyclohex- 1-ene)selenide/bis(2-hydroxymethylcyclohex-1-ene)selenide provide the corresponding spiroselenuranes. The glutathione peroxidase-like...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Switzerland), 2015-07, Vol.20 (7), p.12670-12685
Main Authors: Prasad, Poonam Rajesh, Singh, Harkesh B, Butcher, Ray J
Format: Article
Language:English
Subjects:
antioxidant
Antioxidants
Antioxidants - chemical synthesis
Biomimetic Materials - chemical synthesis
Crystallography, X-Ray
Cyclohexenes - chemistry
Enzymes
glutathione peroxidase (GPx)
Glutathione Peroxidase - chemistry
Molecular Structure
monochalcogenides
Organoselenium Compounds - chemistry
Oxidation
Selenium
Se–O linkage
Single crystals
Spiro Compounds - chemical synthesis
spirodioxychalcogenuranes
Tellurium - chemistry
Thermodynamics
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Summary:Synthesis, structure and antioxidant activity of new cyclohexene-fused spiroselenuranes and a spirotellurane is reported. Oxidation reactions of bis(o-formylcyclohex- 1-ene)selenide/bis(2-hydroxymethylcyclohex-1-ene)selenide provide the corresponding spiroselenuranes. The glutathione peroxidase-like activity of the newly synthesized compounds has been evaluated.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules200712670