Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack

Cement-based grouting material is widely used to reinforce the unsafe rock and control seepage of rock-carved relics although it is considered inappropriate in protection of ancient sites. As this approach is irreversible, a longer service life is desirable for the grouting material and methods to p...

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Published in:Heritage science 2023-11, Vol.11 (1), p.239-11, Article 239
Main Authors: Hu, Wenjing, Fang, Shiqiang, Xie, Lina, Chen, Xueqiang, Zhang, Bingjian
Format: Article
Language:English
Subjects:
Acid rain
Ca2+ ion
Calcium ions
Cement
Chemistry and Materials Science
Cultural heritage
Grout
Grouting
Historic sites
Macrokinetics
Materials Science
Precipitation
Rain
Reaction rate constant
Seepage control
Service life
Stone
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creator Hu, Wenjing
Fang, Shiqiang
Xie, Lina
Chen, Xueqiang
Zhang, Bingjian
description Cement-based grouting material is widely used to reinforce the unsafe rock and control seepage of rock-carved relics although it is considered inappropriate in protection of ancient sites. As this approach is irreversible, a longer service life is desirable for the grouting material and methods to predict the service life are needed. Here we propose a universal formula based on the dissolved amount of calcium ion to predict the deterioration rate of cement-based grout caused by acid deposition in the laboratory. The experimental results showed that the dissolved amount of calcium ion had a linear relationship with ln T and the pH value, with better accuracy when the pH value was greater than 3.0. This work maybe could provide a facile and quantitative method to help us predict the service life of cement-based grouting material under acid rain attack outdoors.
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subjects Acid rain
Ca2+ ion
Calcium ions
Cement
Chemistry and Materials Science
Cultural heritage
Grout
Grouting
Historic sites
Macrokinetics
Materials Science
Precipitation
Rain
Reaction rate constant
Seepage control
Service life
Stone
title Macrokinetics of the deterioration of cement-based grouting material for predicting its service life under acid rain attack
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