Electrochemical and Quantum Chemical Studies on Corrosion Inhibition Performance of 2,2'-(2-Hydroxyethylimino)bis[N-(alphaalpha-dimethylphenethyl)-N-methylacetamide] on Mild Steel Corrosion in 1M HCl Solution

• Published in: Materials research (São Carlos, São Paulo, Brazil) São Paulo, Brazil), 2020-01, Vol.23 (2)
• Main Authors: Danaee, Iman, RameshKumar, S., RashvandAvei, M., Vijayan, M.
• Format: Article
• Language: English
• Subjects: Corrosion inhibitors; ENGINEERING, CHEMICAL; Impedance; MATERIALS SCIENCE, MULTIDISCIPLINARY; METALLURGY & METALLURGICAL ENGINEERING; Potential of zero charge; Quantum chemical calculations
• ISSN: 1516-1439; 1980-5373; 1980-5373
• DOI: 10.1590/1980-5373-mr-2018-0610

Abstract The inhibitory effect of Oxethazaine drug, 2,2'-(2-Hydroxyethylimino)bis[N-(alphaalpha-dimethylphenethyl)-N-methylacetamide] on corrosion of mild steel in 1M HCl solution was studied by weight loss measurements, electrochemical impedance spectroscopy and potentiodynamic polarization methods. The results of gravimetric and electrochemical methods demonstrated that the inhibition efficiency increased with an increase in inhibitor concentration in 1M HCl solution. The results from electrochemical impedance spectroscopy proved that the inhibition action of this drug was due to adsorption on the metal surface. Potentiodynamic polarization studies revealed that the molecule was a mixed type inhibitor. The adsorption of the molecule on the metal surface was found to obey Langmuir Adsorption isotherm. Potential of zero charge at the metal-solution interface was measured to provide the inhibition mechanism. The temperature dependence of the corrosion rate was also studied in the temperature range from 30 to 50 °C. Quantum chemical calculations were applied to correlate electronic structure parameters of the drug with its inhibition performance. The obtained theoretical results have been adapted with the experimental data.