Interplay of Na Substitution in Magnetic Interaction and Photocatalytic Properties of Ca1‐xNaxTi0.5Ta0.5O3 Perovskite Nanoparticles

• Published in: ChemistryOpen (Weinheim) 2024-10, Vol.13 (10), p.e202400021-n/a
• Main Authors: Kammar, S. S., Barote, V. K., Gaikwad, A. A., Shirsath, Sagar E., Ibrahim, A. A., Batoo, K. M., Kadam, R. H., More, S. S.
• Format: Article
• Language: English
• Subjects: Efficiency; Electromagnetic absorption; Electron microscopy; Ferromagnetism; Field emission microscopy; Field emission spectroscopy; Light; Magnetic properties; magnetization; Nanomaterials; Nanoparticles; Oxidation; Perovskites; Photocatalysis; photocatalytic properties; Photodegradation; Pollutants; R&D; Radiation; Research & development; Rhodamine; Semiconductors; Sodium; Sol-gel method; Solar energy; Substitutes; Wastewater treatment; Water treatment; X-ray diffraction
• ISSN: 2191-1363; 2191-1363
• DOI: 10.1002/open.202400021

This research paper delves into the enhancement of wastewater treatment through the design and synthesis of advanced photocatalytic materials, focusing on the effects of sodium (Na) substitution in Ca1‐xNaxTa0.5Ti0.5O3 perovskites. By employing various analytical techniques such as X‐ray diffraction, Field Emission Scanning Electron Microscopy, Transmission Electron Microscopy and UV‐vis spectroscopy, the study examines the transition of these perovskites from tetragonal to orthorhombic structures and observes a reduction in Ca content with Na substitution, which also favors the cubic phase formation and inhibits secondary phases. Significantly, magnetic property analysis uncovers an unexpected ferromagnetic ordering in these perovskites, including compositions traditionally viewed as non‐magnetic. The photocatalytic tests reveal a significant improvement in degrading Rhodamine B dye under visible light, particularly in samples with higher Na levels, attributed to enhanced light absorption and efficient electron processes. The study highlights the optimal Na substitution level for peak photocatalytic performance, offering valuable insights into the complex interplay between structural, magnetic, and photocatalytic properties of these perovskites, and their potential in various applications, thereby contributing to the advancement of wastewater treatment technologies. Photocatalytic process with a scene of water purification and environmental enhancement using Na substituted Ca0.2Ta0.5Ti0.5O3 perovskite nanoparticles. The specific composition, Ca0.2Na0.8Ta0.5Ti0.5O3, exhibits enhanced photocatalytic activity, as demonstrated by reflectance spectra showing bandgap energy and kinetics graphs of photocatalytic degradation. This substitution tailors the material for more effective environmental purification.