Reflectivity and Angular Anisotropy of Liquid Crystal Microcapsules with Different Particle Sizes by Complex Coalescence

• Published in: Molecules (Basel, Switzerland) Switzerland), 2024-06, Vol.29 (13), p.3030
• Main Authors: Yang, Yonggang, Cui, Yuchen, Chen, Yinjie, Guo, Yanan, Liu, Xiaoqi, Chen, Xia, Liu, Jianghao, Liu, Yu, Liu, Zhengfeng
• Format: Article
• Language: English
• Subjects: angular anisotropy; cholesteric liquid crystal microcapsules; complex coacervation; Crystals; Particle size; Polyvinyl alcohol; reflectivity; Temperature
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules29133030

Cholesteric liquid crystal microcapsules (CLCMs) are used to improve the stability of liquid crystals while ensuring their stimulus response performance and versatility, with representative applications such as sensing, anticounterfeiting, and smart fabrics. However, the reflectivity and angular anisotropy decrease because of the anchoring effect of the polymer shell matrix, and the influence of particle size on this has not been thoroughly studied. In this study, the effect of synthesis technology on microcapsule particle size was investigated using a complex coalescence method, and the effect of particle size on the reflectivity and angular anisotropy of CLCMs was investigated in detail. A particle size of approximately 66 µm with polyvinyl alcohol (PVA, 1:1) exhibited a relative reflectivity of 16.6% and a bandwidth of 20 nm, as well as a narrow particle size distribution of 22 µm. The thermosetting of microcapsules coated with PVA was adjusted and systematically investigated by controlling the mass ratio. The optimized mass ratio of microcapsules (66 µm) to PVA was 2:1, increasing the relative reflectivity from 16.6% (1:1) to 32.0% (2:1) because of both the higher CLCM content and the matching between the birefringence of the gelatin-arabic shell system and PVA. Furthermore, color based on Bragg reflections was observed in the CLCM-coated ortho-axis and blue-shifted off-axis, and this change was correlated with the CLCM particle size. Such materials are promising for anticounterfeiting and color-based applications with bright colors and angular anisotropy in reflection.