The Theoretical Description of Cathodic Deposition of New Conducting Polymer Composite, Assisted by a Perrhenate of a Novel Triazolic Derivative

The theoretical description of a new sandwich-like rhenium-based polymer composite cathodic electrodeposition has been given. The cathodic process is realized by perrhenate-ion electrochemical reduction to rhenium (IV) oxide, acting as an in situ formed oxidant for 3,4-dimethoxypyrrole polymerizatio...

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Bibliographic Details
Published in:Orbital : The Electronic Journal of Chemistry 2020-04, Vol.12 (2), p.34-38
Main Authors: Tkach, Volodymyr V, Kushnir, Marta V, Storoshchuk, Nataliia M, Parchenko, Volodymyr V, Aksyonova, Ilona I, Odyntsova, Vira M, Luganska, Olga V, Yagodynets, Petro I
Format: Article
Language:English
Subjects:
assisted polymerization
conducting polymer composites
electrochemical oscillations
Electrochemical reactions
Polymer industry
Polymerization
Polymers
rhenium
stable steady-state
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Summary:The theoretical description of a new sandwich-like rhenium-based polymer composite cathodic electrodeposition has been given. The cathodic process is realized by perrhenate-ion electrochemical reduction to rhenium (IV) oxide, acting as an in situ formed oxidant for 3,4-dimethoxypyrrole polymerization. It is shown that the polymer deposition in this system is realized by more efficient manner than during the direct electropolymerization. The polymer composite has to have a well-developed morphology and enhanced conductivity by sandwich-like structure. The oscillatory behavior, in this case, is also possible, being caused by the DEL influences on both electrochemical and chemical stages of the process. Keywords: conducting polymer composites; rhenium; assisted polymerization; electrochemical oscillations; stable steady-state
ISSN:1984-6428
1984-6428
DOI:10.17807/orbital.v12i2.1193