Interplay of the disorder and strain in gallium oxide

• Published in: Scientific reports 2022-09, Vol.12 (1), p.15366-15366, Article 15366
• Main Authors: Azarov, Alexander, Venkatachalapathy, Vishnukanthan, Karaseov, Platon, Titov, Andrei, Karabeshkin, Konstantin, Struchkov, Andrei, Kuznetsov, Andrej
• Format: Article
• Language: English
• Subjects: 639/301; 639/925; Crystals; Defects; Energy; Gallium; Humanities and Social Sciences; Ion implantation; Irradiation; Materials science; multidisciplinary; Phase transitions; Radiation; Science; Science (multidisciplinary); Semiconductors; Single crystals; X-ray diffraction
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-022-19191-8

Ion irradiation is a powerful tool to tune properties of semiconductors and, in particular, of gallium oxide (Ga 2 O 3 ) which is a promising ultra-wide bandgap semiconductor exhibiting phase instability for high enough strain/disorder levels. In the present paper we observed an interesting interplay between the disorder and strain in monoclinic β-Ga 2 O 3 single crystals by comparing atomic and cluster ion irradiations as well as atomic ions co-implants. The results obtained by a combination of the channeling technique, X-ray diffraction and theoretical calculations show that the disorder accumulation in β-Ga 2 O 3 exhibits superlinear behavior as a function of the collision cascade density. Moreover, the level of strain in the implanted region can be engineered by changing the disorder conditions in the near surface layer. The results can be used for better understanding of the radiation effects in β-Ga 2 O 3 and imply that disorder/strain interplay provides an additional degree of freedom to maintain desirable strain in Ga 2 O 3 , potentially applicable to modify the rate of the polymorphic transitions in this material.