Brief communication: Organochlorine pesticides in an archived firn core from Law Dome, East Antarctica

• Published in: The cryosphere 2016-10, Vol.10 (5), p.2533-2539
• Main Authors: Bigot, Marie, Curran, Mark A. J, Moy, Andrew D, Muir, Derek C. G, Hawker, Darryl W, Cropp, Roger, Teixeira, Camilla F, Bengtson Nash, Susan M
• Format: Article
• Language: English
• Subjects: Archives & records; Arctic zone; Chemicals; Chlordane; Chlorinated solvents; Chlorine compounds; Communication; Contaminants; Contamination; Cryosphere; Dieldrin; Endrin; Firn; Heptachlor; Hexachlorocyclohexane; Ice environments; Insecticides; Laws, regulations and rules; Meltwater; Methods; Organic compounds; Organic contaminants; Organochlorine pesticides; PCB; Pesticides; Pesticides regulation; Polar environments; Polar regions; Polychlorinated biphenyls; Snow; Stainless steel; Storage; Studies
• ISSN: 1994-0424; 1994-0416; 1994-0424; 1994-0416
• DOI: 10.5194/tc-10-2533-2016

Organochlorine pesticides (OCPs) were, for the first time, quantified in archived firn cores from East Antarctica representative of 1945–1957 and 1958–1967 (current era, C.E.). The core sections were melted under high-purity nitrogen atmosphere, and the meltwater was analysed. Methods allowed quantification of hexachlorocyclohexanes, heptachlor, trans-chlordane, dieldrin and endrin. While the core presented evidence of nominal contamination by modern-use chemicals, indicating handling and/or storage contamination, legacy OCP concentrations and deposition rates reported are orders of magnitude lower than those from Arctic regions, lending support for their validity. The study further provides a description of equipment used and suggests methods to overcome logistical challenges associated with trace organic contaminant detection in polar regions.