Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review

With a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle...

Full description

Saved in:
Bibliographic Details
Published in:Frontiers in energy research 2015-01, Vol.3
Main Authors: Zhan eLin, Gaoran eLi, Zhoupeng eLi, Bin eZhang
Format: Article
Language:English
Subjects:
Electrolytes
energy storage
Li-S batteries
polysulfide
review
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue
container_start_page
container_title Frontiers in energy research
container_volume 3
creator Zhan eLin
Gaoran eLi
Zhoupeng eLi
Bin eZhang
description With a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle effects of the sulfur cathode and dendrite formation of the lithium anode are still key limitations to practical use of traditional Li-S batteries. In this review, we focus on the recent developments in electrolyte systems. First we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with traditional liquid cells. We then introduce the most recent progresses in liquid systems, including ether-based, carbonate-based, and ionic liquid-based electrolytes. And then we move on to the advances in solid systems, including polymer and non-polymer electrolytes. Finally, the opportunities and perspectives for future research in both the liquid and solid Li-S batteries are presented.
doi_str_mv 10.3389/fenrg.2015.00005
format article
fullrecord <record><control><sourceid>doaj</sourceid><recordid>TN_cdi_doaj_primary_oai_doaj_org_article_2648a9aae7ad4a6ca781f4ba9662ff65</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_2648a9aae7ad4a6ca781f4ba9662ff65</doaj_id><sourcerecordid>oai_doaj_org_article_2648a9aae7ad4a6ca781f4ba9662ff65</sourcerecordid><originalsourceid>FETCH-LOGICAL-d221t-708a5418748c1d7cf8320490f0b85bd2681bad7dd3111f2e9a358c5202e5848d3</originalsourceid><addsrcrecordid>eNotjc1KAzEURoMgWGr3LvMCU_MzySTuaq1aKQhWwd1wZ3JTU2aakkkrfXuLejYfnMV3CLnhbCqlsbced2kzFYyrKTujLshICKsLZc3nFZkMw_ZsuRSq5GxEXh7wiF3c97jLA42eLjpsc4rdKSNdn4aM_UB9THQV8lc49MX60PlDoveQM6aAwx2d0Tc8Bvy-JpceugEn_zsmH4-L9_lzsXp9Ws5nq8IJwXNRMQPntqlK03JXtd5IwUrLPGuMapzQhjfgKuck59wLtCCVaZVgApUpjZNjsvz7dRG29T6FHtKpjhDqXxHTpoaUQ9thLXRpwAJgBa4E3UJluC8bsFoL77WSP7uEW0s</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review</title><source>ROAD</source><creator>Zhan eLin ; Gaoran eLi ; Zhoupeng eLi ; Bin eZhang</creator><creatorcontrib>Zhan eLin ; Gaoran eLi ; Zhoupeng eLi ; Bin eZhang</creatorcontrib><description>With a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle effects of the sulfur cathode and dendrite formation of the lithium anode are still key limitations to practical use of traditional Li-S batteries. In this review, we focus on the recent developments in electrolyte systems. First we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with traditional liquid cells. We then introduce the most recent progresses in liquid systems, including ether-based, carbonate-based, and ionic liquid-based electrolytes. And then we move on to the advances in solid systems, including polymer and non-polymer electrolytes. Finally, the opportunities and perspectives for future research in both the liquid and solid Li-S batteries are presented.</description><identifier>EISSN: 2296-598X</identifier><identifier>DOI: 10.3389/fenrg.2015.00005</identifier><language>eng</language><publisher>Frontiers Media S.A</publisher><subject>Electrolytes ; energy storage ; Li-S batteries ; polysulfide ; review</subject><ispartof>Frontiers in energy research, 2015-01, Vol.3</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhan eLin</creatorcontrib><creatorcontrib>Gaoran eLi</creatorcontrib><creatorcontrib>Zhoupeng eLi</creatorcontrib><creatorcontrib>Bin eZhang</creatorcontrib><title>Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review</title><title>Frontiers in energy research</title><description>With a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle effects of the sulfur cathode and dendrite formation of the lithium anode are still key limitations to practical use of traditional Li-S batteries. In this review, we focus on the recent developments in electrolyte systems. First we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with traditional liquid cells. We then introduce the most recent progresses in liquid systems, including ether-based, carbonate-based, and ionic liquid-based electrolytes. And then we move on to the advances in solid systems, including polymer and non-polymer electrolytes. Finally, the opportunities and perspectives for future research in both the liquid and solid Li-S batteries are presented.</description><subject>Electrolytes</subject><subject>energy storage</subject><subject>Li-S batteries</subject><subject>polysulfide</subject><subject>review</subject><issn>2296-598X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNotjc1KAzEURoMgWGr3LvMCU_MzySTuaq1aKQhWwd1wZ3JTU2aakkkrfXuLejYfnMV3CLnhbCqlsbced2kzFYyrKTujLshICKsLZc3nFZkMw_ZsuRSq5GxEXh7wiF3c97jLA42eLjpsc4rdKSNdn4aM_UB9THQV8lc49MX60PlDoveQM6aAwx2d0Tc8Bvy-JpceugEn_zsmH4-L9_lzsXp9Ws5nq8IJwXNRMQPntqlK03JXtd5IwUrLPGuMapzQhjfgKuck59wLtCCVaZVgApUpjZNjsvz7dRG29T6FHtKpjhDqXxHTpoaUQ9thLXRpwAJgBa4E3UJluC8bsFoL77WSP7uEW0s</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Zhan eLin</creator><creator>Gaoran eLi</creator><creator>Zhoupeng eLi</creator><creator>Bin eZhang</creator><general>Frontiers Media S.A</general><scope>DOA</scope></search><sort><creationdate>20150101</creationdate><title>Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review</title><author>Zhan eLin ; Gaoran eLi ; Zhoupeng eLi ; Bin eZhang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-d221t-708a5418748c1d7cf8320490f0b85bd2681bad7dd3111f2e9a358c5202e5848d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Electrolytes</topic><topic>energy storage</topic><topic>Li-S batteries</topic><topic>polysulfide</topic><topic>review</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhan eLin</creatorcontrib><creatorcontrib>Gaoran eLi</creatorcontrib><creatorcontrib>Zhoupeng eLi</creatorcontrib><creatorcontrib>Bin eZhang</creatorcontrib><collection>DOAJ Directory of Open Access Journals</collection><jtitle>Frontiers in energy research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhan eLin</au><au>Gaoran eLi</au><au>Zhoupeng eLi</au><au>Bin eZhang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review</atitle><jtitle>Frontiers in energy research</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>3</volume><eissn>2296-598X</eissn><abstract>With a theoretical specific energy 5 times higher than that of lithium-ion (Li-ion) batteries (2,600 vs. ~500 Wh kg-1), lithium-sulfur (Li-S) batteries have been considered as one of the most promising energy storage systems for the electrification of vehicles. However, both the polysulfide shuttle effects of the sulfur cathode and dendrite formation of the lithium anode are still key limitations to practical use of traditional Li-S batteries. In this review, we focus on the recent developments in electrolyte systems. First we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with traditional liquid cells. We then introduce the most recent progresses in liquid systems, including ether-based, carbonate-based, and ionic liquid-based electrolytes. And then we move on to the advances in solid systems, including polymer and non-polymer electrolytes. Finally, the opportunities and perspectives for future research in both the liquid and solid Li-S batteries are presented.</abstract><pub>Frontiers Media S.A</pub><doi>10.3389/fenrg.2015.00005</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier EISSN: 2296-598X
ispartof Frontiers in energy research, 2015-01, Vol.3
issn 2296-598X
language eng
recordid cdi_doaj_primary_oai_doaj_org_article_2648a9aae7ad4a6ca781f4ba9662ff65
source ROAD
subjects Electrolytes
energy storage
Li-S batteries
polysulfide
review
title Developments of Electrolyte Systems for Lithium-Sulfur Batteries: A Review
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T17%3A46%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-doaj&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Developments%20of%20Electrolyte%20Systems%20for%20Lithium-Sulfur%20Batteries:%20A%20Review&rft.jtitle=Frontiers%20in%20energy%20research&rft.au=Zhan%20eLin&rft.date=2015-01-01&rft.volume=3&rft.eissn=2296-598X&rft_id=info:doi/10.3389/fenrg.2015.00005&rft_dat=%3Cdoaj%3Eoai_doaj_org_article_2648a9aae7ad4a6ca781f4ba9662ff65%3C/doaj%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-d221t-708a5418748c1d7cf8320490f0b85bd2681bad7dd3111f2e9a358c5202e5848d3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true