Optimization of chemistry and process parameters for control of intermetallic formation in Mg sludges

• Published in: Journal of magnesium and alloys 2024-04, Vol.12 (4), p.1431-1448
• Main Authors: Fu, Y., Wang, G.G., Hu, A., Li, Y., Thacker, K.B., Weiler, J.P., Hu, H.
• Format: Article
• Language: English
• Subjects: Al-Mn intermetallic; Chemical composition; Magnesium sludge; Optimization; Process parameter; Sludge factor; Taguchi method
• ISSN: 2213-9567; 2213-9567
• DOI: 10.1016/j.jma.2024.04.011

•Identification of the most influencing factor (Mn) for the sludge yield in Mg-Al alloys.•Intermetallic size in the sludge determined primarily by the holding temperature as well as the Al and Mn contents.•Establishment of sludge factors for Mg alloys with multivariate linear regression analyses; and.•Sludge factor equations making the sludge yield and intermetallic size in Mg-Al alloys predictable, which can avoid sludge buildup in holding crucibles, hard spots in cast components, reduced fluidity of liquid metal to flow into a die during casting. Intermetallic formation in sludge during magnesium (Mg) melting, holding and high pressure die casting practices is a very important issue. But, very often it is overlooked by academia, original equipment manufacturers (OEM), metal ingot producers and even die casters. The aim of this study was to minimize the intermetallic formation in Mg sludge via the optimization of the chemistry and process parameters. The Al8Mn5 intermetallic particles were identified by the microstructure analysis based on the Al and Mn ratio. The design of experiment (DOE) technique, Taguchi method, was employed to minimize the intermetallic formation in the sludge of Mg alloys with various chemical compositions of Al, Mn, Fe, and different process parameters, holding temperature and holding time. The sludge yield (SY) and intermetallic size (IS) was selected as two responses. The optimum combination of the levels in terms of minimizing the intermetallic formation were 9 wt.% Al, 0.15 wt.%Mn, 0.001 wt.% (10 ppm) Fe, 690 °C for the holding temperature and holding at 30 mins for the holding time, respectively. The best combination for smallest intermetallic size were 9 wt.% Al, 0.15 wt.%Mn, 0.001 wt.% (10 ppm) Fe, 630 °C for the holding temperature and holding at 60 mins for the holding time, respectively. Three groups of sludge factors, Chemical Sludge (CSF), Physical Sludge (PSF) and Comprehensive Sludge Factors (and CPSF) were established for prediction of sludge yields and intermetallic sizes in Al-containing Mg alloys. The CPSF with five independent variables including both chemical elements and process parameters gave high accuracy in prediction, as the prediction of the PSF with only the two processing parameters of the melt holding temperature and time showed a relatively large deviation from the experimental data. The Chemical Sludge Factor was primarily designed for small ingot producers and die casters with a limited melting and