Crystal structure of N , N '-[(ethane-1,2-di-yl)bis-(aza-nediylcarbono-thio-yl)]bis-(benzamide)

The reaction of benzoyl chloride and ethyl-endi-amine in the presence of potassium thio-cyanate yielded a white solid, C H N O S , which consists of two benzoyl-thio-ureido moieties connected by an ethyl-ene chain. The asymmetric unit consists of one half of the mol-ecule, the complete mol-ecule bei...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-05, Vol.75 (Pt 5), p.642-645
Main Authors: Samb, Issa, Gaye, Nango, Sylla-Gueye, Rokhaya, Thiam, Elhadj Ibrahima, Gaye, Mohamed, Retailleau, Pascal
Format: Article
Language:English
Subjects:
benzoylthioureido
Chemical Sciences
Coordination chemistry
Cristallography
crystal structure
ethylenediamine
Research Communications
thiourea
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Summary:The reaction of benzoyl chloride and ethyl-endi-amine in the presence of potassium thio-cyanate yielded a white solid, C H N O S , which consists of two benzoyl-thio-ureido moieties connected by an ethyl-ene chain. The asymmetric unit consists of one half of the mol-ecule, the complete mol-ecule being generated by crystallographic inversion symmetry. Both thio-urea moieties are in a conformation. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, C-H⋯S and C-H⋯O hydrogen bonds link the molecules, forming layers parallel to the plane.
ISSN:2056-9890
2056-9890
DOI:10.1107/S205698901900495X